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Russian Journal of General Chemistry

, Volume 88, Issue 10, pp 2108–2113 | Cite as

Effect of the Solvent on the Coordination of Pyridine Derivatives with Zn Tetraphenylporphine

  • V. P. AndreevEmail author
  • P. S. Sobolev
  • D. O. Zaitsev
  • S. M. Timofeeva
Article
  • 10 Downloads

Abstract

The coordination of zinc(II) tetraphenylporphine with pyridines was studied by electronic spectroscopy. Linear correlations were found between the thermodynamic and kinetic parameters of coordination in different solvents. The effect of the solvent on the stability constants of the complexes and the thermodynamics of complex formation are discussed.

Keywords

complex formation coordination Zn tetraphenylporphine pyridines solvent effects 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • V. P. Andreev
    • 1
    Email author
  • P. S. Sobolev
    • 1
  • D. O. Zaitsev
    • 1
  • S. M. Timofeeva
    • 2
  1. 1.Petrozavodsk State UniversityPetrozavodskRussia
  2. 2.Moscow Institute of Fine Chemical TechnologiesMoscowRussia

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