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Russian Journal of General Chemistry

, Volume 88, Issue 10, pp 2103–2107 | Cite as

Basic and Coordination Properties of Tetraphenylporphine Derivatives

  • Yu. B. IvanovaEmail author
  • A. O. Plotnikova
  • A. S. Semeikin
  • S. G. Pukhovskaya
  • N. Zh. Mamardashvili
Article

Abstract

Basic and coordination properties of 5,10,15,20-tetrakis(3,5-dibromophenyl)porphine and 5,10,15,20-tetrakis(4-methoxy-3-bromophenyl)porphine in acetonitrile have been investigated by means of spectrophotometry. The optimization of the geometry parameters of polysubstituted porphyrins has been performed using quantum-chemical method (РМ3). The relationship between geometric structure of the studied porphyrins and their coordination, basic, and spectral properties is discussed.

Keywords

porphyrins basic properties metal porphyrins coordination properties 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • Yu. B. Ivanova
    • 1
    Email author
  • A. O. Plotnikova
    • 2
  • A. S. Semeikin
    • 2
  • S. G. Pukhovskaya
    • 2
  • N. Zh. Mamardashvili
    • 1
  1. 1.Krestov Institute of Solutions ChemistryRussian Academy of SciencesIvanovoRussia
  2. 2.Ivanovo State University of Chemistry and TechnologyIvanovoRussia

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