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Russian Journal of General Chemistry

, Volume 88, Issue 10, pp 2084–2088 | Cite as

(Iodomethyl)fluorosilanes: Synthesis and Reactions

  • B. А. Gostevskii
  • N. F. LazarevaEmail author
Article
  • 12 Downloads

Abstract

The methods of synthesis of bifunctional (iodomethyl)fluorosilanes of general formula ICH2SiMenF3–n (n = 0, 2) have been elaborated; the structure was proved by 1H, 13C, 29Si NMR spectroscopy. The reaction of (iodomethyl)dimethylfluorosilane with O-trimethylsilyl derivative of N,N'-dimethylhydrazide of trifluoroacetic acid gives rise to the formation of 2,2,4,4-tetramethyl-6-(trifluoromethyl)-3,4-dihydro-2Н-1,4,5,2-oxadiasilin-4-ium iodide with tetracoordinate silicone atom.

Keywords

(iodomethyl)trifluorosilane (iodomethyl)dimethylfluorosilane (halogenomethyl)halogenosilanes α-carbofunctional silanes 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.A.E. Favorskii Irkutsk Institute of Chemistry, Siberian BranchRussian Academy of SciencesIrkutskRussia

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