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Russian Journal of General Chemistry

, Volume 88, Issue 10, pp 2050–2057 | Cite as

Some New Reactions and Properties of Xanthane Hydride (5-Amino-1,2,4-dithiazole-3-thione)

  • V. V. DotsenkoEmail author
  • T. Yu. Evmeshchenko
  • N. A. Aksenov
  • I. V. Aksenova
  • G. D. Krapivin
  • D. I. Sharapa
  • F. F. Chausov
  • V. D. Strelkov
  • L. V. Dyadyuchenko
Article
  • 25 Downloads

Abstract

Aminomethylation of xanthane hydride (5-amino-1,2,4-dithiazole-3-thione) with the RNH2–HCHO system has resulted in the formation of the derivatives of new heterocyclic system (3,7-dihydro-5H-[1,2,4]-dithiazolo[4,3-a][1,3,5]triazine) in low yields. The reaction of xanthane hydride with dicyandiamide has led to thioammeline [4,6-diamino-1,3,5-triazine-2(5Н)-thione]. Some practically important properties of xanthane hydride and its derivatives have been investigated. Xanthane hydride has efficiently exhibited carbon steel corrosion in neutral aqueous media. The prepared compounds have not exhibited growth-regulating or antidote activity to herbicide 2,4-D.

Keywords

xanthane hydride 5H-[1,2,4]dithiazolo[4,3-a][1,3,5]triazin-3-thione dicyandiamide thioammeline Mannich reaction 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • V. V. Dotsenko
    • 1
    • 2
    Email author
  • T. Yu. Evmeshchenko
    • 1
  • N. A. Aksenov
    • 2
  • I. V. Aksenova
    • 2
  • G. D. Krapivin
    • 3
  • D. I. Sharapa
    • 4
  • F. F. Chausov
    • 5
  • V. D. Strelkov
    • 1
    • 6
  • L. V. Dyadyuchenko
    • 6
  1. 1.Kuban State UniversityKrasnodarRussia
  2. 2.North-Caucasus Federal UniversityStavporolRussia
  3. 3.Kuban State Technological UniversityKrasnodarRussia
  4. 4.Institute of Catalysis Research and TechnologyKarlsruhe Institute of TechnologyKarlsruheGermany
  5. 5.Udmurt Federal Research Center, Ural BranchRussian Academy of SciencesIzhevskRussia
  6. 6.All-Russian Research Institute of Biological Protection of PlantsKrasnodarRussia

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