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Russian Journal of General Chemistry

, Volume 88, Issue 10, pp 2039–2043 | Cite as

Unusual Reaction of Sodium 1,6-Dioxo-2,4-alkadiene-3,4-diolates under Acid Hydrolysis Conditions

  • P. P. MukovozEmail author
  • P. A. Slepukhin
  • I. N. Ganebnykh
  • O. S. El’tsov
  • E. A. Danilova
Article
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Abstract

The reaction of sodium 1,6-dioxo-2,4-alkadiene-3,4-diolates with HCl solution afforded unexpected hydrolysis products, namely (2Z)-2-hydroxy-4-oxobut-2-enoic (2,4-dioxobutanoic) acid esters. The structural features of the synthesized compounds were discussed on the basis of IR, 1H NMR spectroscopy, mass spectrometry and X-ray diffraction analysis data.

Keywords

sodium 1,6-dioxo-2,4-alkadiene-3,4-diolate 1,3,4,6-tetracarbonyl compounds (2Z)-2-hydroxy-4-oxobut-2-enoic (2,4-dioxobutanoic) acid esters 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • P. P. Mukovoz
    • 1
    Email author
  • P. A. Slepukhin
    • 2
    • 3
  • I. N. Ganebnykh
    • 2
    • 3
  • O. S. El’tsov
    • 3
  • E. A. Danilova
    • 4
  1. 1.All-Russian Research Institute of PhytopathologyBol’shiye Vyazemy, Moscow oblastRussia
  2. 2.Postovskii Institute of Organic SynthesisYekaterinburgRussia
  3. 3.Ural Federal University named after the first President of Russia B. N. YeltsinYekaterinburgRussia
  4. 4.Ivanovo State University of Chemistry and TechnologyIvanovoRussia

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