Abstract
The system thiourea dioxide–hydrogen peroxide is found to effectively hydroxylate coumarin in aqueous solutions. The hydroxyl radical reacting with coumarin is shown to result from decomposition of the complex thiourea dioxide–H2O2. The obtained data are compared to the results of investigation of the reactions occurring in the system thiourea dioxide–H2O2 with terephthalic acid.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Makarov, S.V., Horváth, A.K., Silaghi-Dumitrescu, R., and Gao, Q., Sodium Dithionite, Rongalite and Thiourea Oxides. Chemistry and Application, Singapore: World Scientific, 2016.
Makarov, S.V., Horváth, A.K., Silaghi-Dumitrescu, R., and Gao, Q., Chem. Eur. J., 2014, vol. 20, p. 14164. doi 10.1002/chem.201403453
Makarov, S.V., Russ. Chem Rev., 2001, vol. 70, no. 10, p. 885. doi 10.1070/RC2001v070n10ABEH000659
Verma, S., Kumar, S., Jain, S.L., and Sain, B., Org. Biomol. Chem., 2011, vol. 9, p. 6943. doi 10.1039/c1ob05818e
Verma, S. and Jain, S.L., Tetrahedron Lett., 2012, vol. 53, p. 6055. doi 10.1016/j.tetlet.2012.08.118
Verma, S., Singh, R., Tripathi, D., Gupta, P., Bahuguna, G.M., and Jain, S.L., RSC Adv., 2013, vol. 3, p. 4184. doi 10.1039/c3ra21971b
Hebeish, A., El-Rafie, M.H., Waly, A., and Moursi, A.Z., J. Appl. Polym. Sci., 1978, vol. 22, p. 1853. doi 10.1002/app.1978.070220709
Vlasova E.A., Kuznetsova A.A., Golovashova E.S., and Makarov, S.V., Russ. J. Gen. Chem., 2017, vol. 87, no. 4, p. 698. doi 10.1134/S1070363217040065
Czili, H. and Horváth, A., Appl. Catal. (B), 2008, vol. 81, p. 295. doi 10.1016/j.apcatb.2008.01.001
Wang, Z., Lv, K., Wang, G., Deng, K., and Tang, D., Appl. Catal. (B), 2010, vol. 100, p. 378. doi 10.1016/j.apcatb.2010.08.014
Wagner, B.D., Molecules, 2009, vol. 14, p. 210. doi 10.3390/molecules14010210
Jung, J.-C. and Park, O.-S., Molecules, 2009, vol. 14, p. 4790. doi 10.3390/molecules14114790
Guan, H., Zhu, L., Zhou, H., and Tang, H., Anal. Chim. Acta, 2008, vol. 608, p. 73. doi 10.1016/j.aca.2007.12.009
Louit, G., Foley, S., Cabillic, J., Coffigny, H., Taran, F., Valleix, A., Renault, J.F., and Pin, S., Radiat. Phys. Chem., 2005, vol. 72, p.119.
Gao, Q., Liu, B., Li, L., and Wang, J., J. Phys. Chem. (A), 2007, vol. 111, p. 872. doi 10.1021/jp063956qCCC
Ferrari, A.M., Sgobba, M., Gamberini, M.C., and Rastelli, G., Eur. J. Med. Chem., 2007, vol. 42, p. 1028. doi 10.1016/j.ejmech.2006.12.023
Kadla, J., Chang, H.-M., Chen, L., and Gratzl, J.S., Hofzforschung, 1998, vol. 52, p. 513. doi 10.1515/hfsg.1998.52.5.513
Kadla, J.F. and Cornman, C.R., J. Chem. Soc. Perkin Trans. 2, 1998, p. 2309. doi 10.1039/A801251B
Foley, S., Rotureau, P., Pin, S., Baldacchino, G., Renault, J.-F., and Mialocq, J.-C., Angew. Chem. Int. Ed., 2005, vol. 44, p. 110. doi 10.1002/anie.200460284
Charbouillot, T., Brigante, M., Mailhot, G., Maddigapu, P.R., Minero, C., and Vione, D., J. Photochem. Photobiol. (A), 2011, vol. 222, p. 70. doi 10.1016/j.jphotochem.2011.05.003
Wang, W., Schuchmann, M.N., Schuchmann, H.-P., Knolle, W., von Sonntag, J., and von Sonntag, C., J. Am. Chem. Soc., 1999, vol. 121, p. 238. doi 10.1021/ja983275b
Christensen, H., Sehested, K., and Corfitzen, H., J. Phys. Chem., 1982, vol. 86, p. 1588. doi 10.1021/j100206a023
Lou, E.K., Cathro, P., Marino, V., Damiani, F., and Heithersay, G.S., J. Endod., 2016, vol. 42, p. 1126. doi 10.1016/j.joen.2016. 04.010
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © P.А. Molodtsov, А.S. Makarova, S.V. Makarov, А.А. Kuznetsova, О.I. Koifman, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 6, pp. 905–908.
Rights and permissions
About this article
Cite this article
Molodtsov, P.A., Makarova, A.S., Makarov, S.V. et al. Reaction of Thiourea Dioxide and Hydrogen Peroxide with Coumarin. Russ J Gen Chem 88, 1086–1089 (2018). https://doi.org/10.1134/S1070363218060063
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363218060063