Russian Journal of General Chemistry

, Volume 88, Issue 3, pp 505–508 | Cite as

Six-Nuclear Complexes of Platinum(II) and Palladium(II) with Mercamine and β-Mercaptoethanol

  • A. N. Azizova
  • D. B. Tagiev
  • Sh. G. Kasumov
  • Kh. I. Gasanov
Article
  • 3 Downloads

Abstract

The platinum(II) and palladium(II) complexes [Pt6(SCH2CH2NH2)8]Cl4 and [Pd6(SCH2CH2OH)8 Cl4· 5H2O with mercamine and β-mercaptoethanol, respectively, were synthesized. It was found on the basis of the comparison of IR and X-ray electron spectra of the ligands and complexes, and also of the data of X-ray diffraction analysis that the bidentate coordination of ligands through sulfur and nitrogen atoms is realized in the platinum(II) complex. In the palladium(II) complex β-mercaptoethanol is coordinated in a mixed-mode type. In both complexes sulfur atoms of the ligands occupy a bridging position.

Keywords

mercamine platinum and palladium complexes chelating six-nuclear type of coordination mixed coordination 

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • A. N. Azizova
    • 1
  • D. B. Tagiev
    • 1
  • Sh. G. Kasumov
    • 2
  • Kh. I. Gasanov
    • 2
  1. 1.Academician M. Nagiev Institute of Catalysis and Inorganic ChemistryNational Academy of Sciences of AzerbaijanBakuAzerbaijan
  2. 2.Azerbaijan Medical UniversityBakuAzerbaijan

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