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Russian Journal of General Chemistry

, Volume 87, Issue 1, pp 37–43 | Cite as

Nucleophilic addition of aromatic amide oximes to [2-B10H9NCC2H5] anion

  • D. S. Bolotin
  • M. Ya. Demakova
  • E. A. Daines
  • M. S. Avdontseva
  • A. P. Zhdanov
  • K. Yu. Zhizhin
  • N. T. Kuznetsov
Article

Abstract

A series of closo-decaborate anions containing an O-iminoacylamide oxime fragment were synthesized by nucleophilic addition of aromatic amide oximes to 2-propionitrilium closo-decaborate anion. The isolated compounds were characterized by IR, 1H, 13C–{1H}, and 11B–{1H} NMR, and mass spectra. The structure of (Ph4P)[2-B10H9NH=C(Et)ON=C(NH2)C6H4Me-2] was determined by single-crystal X-ray analysis.

Keywords

closo-decaborate anion nitrilium derivatives nucleophilic addition amide oximes oximes 

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • D. S. Bolotin
    • 1
  • M. Ya. Demakova
    • 1
  • E. A. Daines
    • 1
  • M. S. Avdontseva
    • 1
  • A. P. Zhdanov
    • 2
  • K. Yu. Zhizhin
    • 2
  • N. T. Kuznetsov
    • 2
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia
  2. 2.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia

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