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Russian Journal of General Chemistry

, Volume 86, Issue 12, pp 2682–2688 | Cite as

Kinetics and mechanism of oxidative polymerization of phenylenediamines

  • I. S. Strakhov
  • Ya. O. MezhuevEmail author
  • Yu. V. Korshak
  • M. I. Stilman
Article

Abstract

Kinetics of oxidative polymerization of three isomeric phenylenediamines in aqueous hydrochloric acid solutions initialed by ammonium persulfate has been studied, and kinetic parameters of non-catalytic and catalytic stages of polymerization have been determined. The observed effect of the isomeric substrates structure on the activation energy of the catalytic and non-catalytic stages has been explained.

Keywords

phenylenediamine oxidative polymerization kinetics mechanism 

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Copyright information

© Pleiades Publishing, Ltd. 2016

Authors and Affiliations

  • I. S. Strakhov
    • 1
  • Ya. O. Mezhuev
    • 1
    Email author
  • Yu. V. Korshak
    • 1
  • M. I. Stilman
    • 1
  1. 1.Mendeleev University of Chemical Technology of RussiaMoscowRussia

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