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Russian Journal of General Chemistry

, Volume 86, Issue 12, pp 2671–2676 | Cite as

Synthesis and structure of tri(o-tolyl) antimony dioximates

  • V. V. SharutinEmail author
  • O. K. Sharutina
  • E. V. Artem’eva
  • M. S. Makerova
Article
  • 34 Downloads

Abstract

Tri(o-tolyl) antimony dioximates were synthesized by the reaction of tri(o-tolyl) antimony with 5-nitrofurfural and thiophen-2-carbaldehyde oximes in ether in the presence of hydrogen peroxide or tert-butylhydroperoxide (1: 2: 1 mol). Antimony atoms in the reaction products have distorted trigonal-bipyramidal coordination with the intramolecular distances Sb···N shorter than the sum of the van der Waals radii of Sb and N by ~1 Å.

Keywords

dioximates tri(o-tolyl)antimony oximes X-ray structural analysis 

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Copyright information

© Pleiades Publishing, Ltd. 2016

Authors and Affiliations

  • V. V. Sharutin
    • 1
    Email author
  • O. K. Sharutina
    • 1
  • E. V. Artem’eva
    • 1
  • M. S. Makerova
    • 1
  1. 1.National Research South Ural State UniversityChelyabinskRussia

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