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Russian Journal of General Chemistry

, Volume 85, Issue 12, pp 2793–2800 | Cite as

Synthesis and crystal structure of thiolate-bridged dinuclear platinum(II) complexes

  • R. V. Suezov
  • A. V. Eremin
  • V. V. Gurzhii
  • N. L. Medvedskii
  • A. N. Belyaev
Article
  • 49 Downloads

Abstract

Reactions of 2,2′-bipyridine platinum(II) complexes with 2-aminoethanethiol or 2,2′-disulfanediyldi-(ethan-1-amine) afforded new complexes [Pt2(μ-aet)(μ-aetH+)(bpy)2](NO3)4 · 2H2O and [Pt2(μ-aet)(μ-aetH+)· (bpy)2](NO3)4 ·5H2O and heteronuclear complex catena-[(bpy)Pt(μ-aet)Ag](NO3)2 · 3H2O (bpy = 2,2′-bipyridine, aet = 2-aminoethanethiol). All complexes were characterized by elemental analyses and X-ray diffraction data.

Keywords

platinum dinuclear complexes thiolate complexes crystal structure 2-aminoethanethiol 

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • R. V. Suezov
    • 1
  • A. V. Eremin
    • 1
  • V. V. Gurzhii
    • 2
  • N. L. Medvedskii
    • 1
  • A. N. Belyaev
    • 1
  1. 1.St. Petersburg State Institute of TechnologySt. PetersburgRussia
  2. 2.St. Petersburg State UniversitySt. PetersburgRussia

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