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Russian Journal of General Chemistry

, Volume 85, Issue 6, pp 1382–1385 | Cite as

Reaction of α-carbanions of lithium acylates with 1,2-dibromoethane

  • A. V. ZorinEmail author
  • A. T. Zaynashev
  • A. R. Chanysheva
  • V. V. Zorin
Article

Abstract

The reaction of 1,2-dibromoethane with α-carbanions of lithium acylates generated from acetic, butyric, isobutyric, and capronic acids with lithium diisopropylamide has been studied. Anion-radical and anionic pathways of the products formation have been discussed.

Keywords

1,2-dibromoethane dicarboxylic acid enolate anion carbanion metalation oxidative coupling 

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • A. V. Zorin
    • 1
    Email author
  • A. T. Zaynashev
    • 1
  • A. R. Chanysheva
    • 1
  • V. V. Zorin
    • 1
  1. 1.Ufa State Petroleum Technological UniversityUfaRussia

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