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Russian Journal of General Chemistry

, Volume 84, Issue 4, pp 719–721 | Cite as

Synthesis and structure of novel dinitrosyl iron complexes [Fe2(μ-SCH2CH2NHR)2(NO)4]

  • P. B. Davidovich
  • V. V. Gurzhy
  • A. N. Belyaev
Article

Abstract

Two novel dinitrosyl iron complexes with thiolate bridging ligands [Fe2(μ-SCH2CH2NHR)2(NO)4] (R = Ac, Boc), derived from the cysteamine complex [Fe2(μ-SCH2CH2NH3)2(NO)4]2+ are described. The complex with acylated cysteamine is characterized by X-ray diffraction analysis. The cysteamine complex is a convenient precursor for modification of the bridging ligand.

Keywords

coordination compounds of iron nitrogen monoxide donors structure DFT calculations 

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Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  • P. B. Davidovich
    • 1
  • V. V. Gurzhy
    • 2
  • A. N. Belyaev
    • 1
  1. 1.St. Petersburg State Institute of Technology (Technical University)St. PetersburgRussia
  2. 2.St. Petersburg State UniversitySt. PetersburgRussia

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