Russian Journal of General Chemistry

, Volume 82, Issue 8, pp 1432–1437 | Cite as

Synthesis, photochromic properties, and complex formation with metal ions of hydrazones based on a spiropyran of oxaindane series

  • L. D. Popov
  • I. A. Shcherbakov
  • A. O. Bulanov
  • E. Yu. Shasheva
  • Yu. N. Tkachenko
  • O. I. Kobeleva
  • T. M. Vyalova
  • V. A. Barachevskii
Article
  • 93 Downloads

Abstract

A series of hydrazones based on a new spiropyran oxaindane series was synthesized. The compounds were found to possess photochromism and are characterized by a high rate of spontaneous decoloration of their photoinduced merocyanine form. Dark and photoinduced formation of complex compounds in the reaction of metal ions with molecules of the hydrazones in solution was observed.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Barachevskii, V.A., Khim. Vysokikh Energii, 2003, vol. 37, no. 1, p. 8.Google Scholar
  2. 2.
    Bren’, V.A., Usp. Khim., 2001, vol. 70, no. 12, p. 1152.Google Scholar
  3. 3.
    Duerr, Ed. H. and Bouas-Laurent, H., Photochromism. Molecules and Systems, Amsterdam: Elsever, 1990.Google Scholar
  4. 4.
    Zakharova, M.I., Pimienta, V., Metelitsa, A.V., Minkin, V.I., and Misho, Zh.K., Ross. Khim. Zh., 2007, vol. 11, no. 6, p. 71.Google Scholar
  5. 5.
    Bulanov, A.O., Popov, L.D., Shcherbakov, I.N., Kogan, V.A, Barachevsky, V.A., Lukov, V.V., Borisenko, S.N., and Tkachenko, Yu.N., Spectrochim. Acta, A, 2008, vol. 71, no. 3, p. 1146.CrossRefGoogle Scholar
  6. 6.
    Popov, L.D., Shcherbakov, I.N., Kogan, V.A., Kobeleva, O.I., Valova, T.M., Barachevskii, V.A., Shienok, A.I., Kol’tsova, L.S., and Zaichenko, N.L., Izv. Akad. Nauk, Ser. Khim., 2009, no. 5, p. 950.Google Scholar
  7. 7.
    Barachevskii, V.A., Kobeleva, O.I., Valova, T.M., Popov, L.D., Shcherbakov, I.N., Bulanov, A.O, and Kogan, V.A., Ross. Khim. Zh., 2009, vol. 53, no. 1, p. 110.Google Scholar
  8. 8.
    Bulanov, A.O., Shcherbakov, I.N., Popov, L.D., Shasheva, E.Y. Belikov, P.A., and Starikova, Z.A., Acta Cryst., C, 2011, vol. 67, p. 85.CrossRefGoogle Scholar
  9. 9.
    Bulanov, A.O., Shcherbakov, I.N., Tupolova, Y.P., Popov, L.D., and Lukov, V.V., Kogan, V.A., Belikov, P.A., Acta Cryst., C, 2009, vol. 65, p. 618.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2012

Authors and Affiliations

  • L. D. Popov
    • 1
  • I. A. Shcherbakov
    • 1
  • A. O. Bulanov
    • 1
  • E. Yu. Shasheva
    • 1
  • Yu. N. Tkachenko
    • 1
  • O. I. Kobeleva
    • 2
  • T. M. Vyalova
    • 2
  • V. A. Barachevskii
    • 2
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Center of PhotochemistryRussian Academy of SciencesMoscowRussia

Personalised recommendations