Russian Journal of General Chemistry

, Volume 80, Issue 9, pp 1853–1859 | Cite as

Physicochemical study of binuclear copper(II), oxovanadium(IV), and iron(III) complexes with bis-1′-phthalazinylhydrazone of 2,6-diformyl-4-tert-butylphenol

  • L. D. Popov
  • S. I. Levchenkov
  • I. N. Shcherbakov
  • Yu. P. Tupolova
  • A. A. Zubenko
  • I. E. Melkozerova
  • V. V. Lukov
  • V. A. Kogan
Article

Abstract

Binuclear copper(II), oxovanadium(IV), and iron(III) complexes with bis-1′-phthalazinylhydrazone of 2,6-diformyl-4-tert-butylphenol have been prepared. An antiferromegnetic exchange interaction between the paramagnetic centers was found. Redox properties of the complexes were studied by the methods of cyclic and differential pulse voltammetry; the reduction of Cu(II) complexes was shown to proceed in two consecutive one-electron steps.

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Copyright information

© Pleiades Publishing, Ltd. 2010

Authors and Affiliations

  • L. D. Popov
    • 1
  • S. I. Levchenkov
    • 2
  • I. N. Shcherbakov
    • 1
  • Yu. P. Tupolova
    • 1
  • A. A. Zubenko
    • 3
  • I. E. Melkozerova
    • 1
  • V. V. Lukov
    • 1
  • V. A. Kogan
    • 1
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Scientific Center of Russian Academy of SciencesRostov-on-DonRussia
  3. 3.North-Caucasus Regional Research Veterinary InstituteNovocherkasskRussia

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