Russian Journal of General Chemistry

, Volume 79, Issue 12, pp 2723–2730 | Cite as

Uranyl selenates with organic templates: Principles of structure and characteristics of self-organization

  • S. V. Krivovichev
  • V. V. Gurzhiy
  • I. G. Tananaev
  • B. F. Myasoedov
Article

Abstract

Basic structural principles of uranyl selenates with organic templates are outlined as follows. In compounds with short chain amine molecules (C:N < 8) the primary role plays the correspondence between topology of inorganic complex (isomerism) and structure and shape of a template. In the structures with long chain molecules (C:N ≤ 8), the molecules are associated to form 2- or 1-dimensional supramolecular templates that are connected with inorganic structure according to the charge density matching principle. Compounds with electro neutral molecules (crown ethers) have composite structure, where bonding between organic and inorganic parts is achieved through hydrogen bonding via intermediate oxonium clusters.

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Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • S. V. Krivovichev
    • 1
  • V. V. Gurzhiy
    • 1
  • I. G. Tananaev
    • 2
  • B. F. Myasoedov
    • 2
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia
  2. 2.Institute of Geochemistry and Analytical ChemistryMoscowRussia

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