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Russian Journal of General Chemistry

, Volume 76, Issue 6, pp 992–996 | Cite as

Complexing properties of ambidentate benzo-15-crown-5-substituted azomethine ligands

  • A. S. Burlov
  • A. V. Tsukanov
  • G. S. Borodkin
  • Yu. V. Revinskii
  • A. D. Dubonosov
  • V. A. Bren’
  • A. D. Garnovskii
  • A. Yu. Tsivadze
  • V. I. Minkin
Article

Abstract

Crown-containing azomethines and their zinc complexes were prepared. Examination of their structure by 1H and 7Li NMR and electronic spectroscopy showed that, in accordance with the concept of hard and soft acids and bases, the hard lithium cation coordinates to the crown ether fragment with the formation of mono-(Li) and binuclear (Li, Zn) complexes.

Keywords

General Chemistry Crown Ether Electronic Absorption Spectrum Zinc Complex Crown Ether Moiety 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Inc. 2006

Authors and Affiliations

  • A. S. Burlov
    • 1
  • A. V. Tsukanov
    • 1
  • G. S. Borodkin
    • 1
  • Yu. V. Revinskii
    • 1
  • A. D. Dubonosov
    • 2
  • V. A. Bren’
    • 1
  • A. D. Garnovskii
    • 1
  • A. Yu. Tsivadze
    • 3
  • V. I. Minkin
    • 1
  1. 1.Research Institute of Physical and Organic ChemistryRostov State UniversityRostov-on-DonRussia
  2. 2.Southern Scientific CenterRussian Academy of SciencesRoston-on-DonRussia
  3. 3.Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussia

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