Advertisement

Russian Journal of Coordination Chemistry

, Volume 45, Issue 12, pp 867–875 | Cite as

Cu(II), Ni(II), and Co(II) Complexes of Tetradentate Azomethine Ligands: Chemical and Electrochemical Syntheses, Crystal Structures, and Magnetic Properties

  • T. V. Lifintseva
  • A. S. BurlovEmail author
  • V. G. Vlasenko
  • Yu. V. Koshchienko
  • D. A. Garnovskii
  • S. A. Mashchenko
  • S. I. Levchenkov
  • V. A. Lazarenko
  • V. N. Khrustalev
  • A. L. Trigub
Article
  • 17 Downloads

Abstract

Complexes CuL1 ⋅ MeOH (Ia), NiL1 ⋅ MeOH (Ib), CоL1 ⋅ MeOH (Ic), CuL2 (IIa), NiL2 (IIb), and CоL2 (IIc) of the tetradentate azomethine compounds, namely, 4-methyl-N-[2-[(E)-2-[2-[2-[(E)-[2-(p-toluenesulfamino)phenyl]methyleneamino]ethoxy]ethyliminomethyl]phenyl]benzenesulfamide (H2L1) and 4-methyl-N-[2-[(E)-3-[4-[3-[(E)-[2-(p-toluenesulfamino)phenyl]methyleneamino]propoxy]butoxy]-propyliminomethyl]phenyl]benzenesulfamide (H2L2), which are the condensation products of 2-(N-tosylamino)benzaldehyde with 3,4-dioxa-1,8-octanediamine and 4,9-dioxa-1,12-dodecanediamine, are synthesized using the chemical and electrochemical methods. The structures, compositions, and properties of the synthesized metal complexes are studied by the methods of elemental analysis, IR spectroscopy, X-ray absorption spectroscopy, magnetochemistry, and X-ray diffraction analysis (СIF files CCDC nos. 1910746 (Ia), 1910747 (Ib), and 1910748 (Ic)). In the molecules of compounds IaIc, the L1 macrocyclic ligand coordinates the metal atom by four nitrogen atoms via the tetradentate chelate mode to form the polyhedron as a distorted tetrahedron.

Keywords:

tetradentate Schiff bases electrochemical synthesis metal complexes magnetic properties X-ray diffraction analysis 

Notes

ACKNOWLEDGMENTS

The equipment of the unique scientific setup “Kurchatov Synchrotron Radiation Source” supported by the Ministry of Education and Science of the Russian Federation (project no. RFMEFI61914X0002) was used. The IR and 1Н NMR spectra were recorded using the equipment of the Center for Collective Use “Molecular Spectroscopy.”

FUNDING

This work was supported by the Southern Federal University.

CONFLICT OF INTEREST

The authors declare that they have no conflicts of interest.

REFERENCES

  1. 1.
    Cozzi, P.G., Chem. Soc. Rev., 2004, vol. 33, p. 410.  https://doi.org/10.1039/b307853c CrossRefPubMedGoogle Scholar
  2. 2.
    Gupta, K.C. and Sutar, A.K., Coord. Chem. Rev., 2008, vol. 252, nos 12–14, p. 1420.  https://doi.org/10.1016/j.ccr.2007.09.005 CrossRefGoogle Scholar
  3. 3.
    Pawanoji, A.A. and Mehta, B.H., Imper. J. Interdiscipl. Res., 2016, vol. 2, no. 12, p. 448.Google Scholar
  4. 4.
    Burlov, A.S., Vlasenko, V.G., Garnovskii, D.A., et al., Russ. J. Inorg. Chem., 2014, vol. 59, p. 721.  https://doi.org/10.1134/S0036023614070031 CrossRefGoogle Scholar
  5. 5.
    Burlov, A.S., Vlasenko, V.G., Koshchienko, Yu.V., et al., Polyhedron, 2018, vol. 144, p. 249.  https://doi.org/10.1016/j.poly.2018.01.020 CrossRefGoogle Scholar
  6. 6.
    Burlov, A.S., Mal’tsev, E.I., Vlasenko, V.G., et al., Polyhedron, 2017, vol. 133, p. 231.  https://doi.org/10.1016/j.poly.2017.05.045 CrossRefGoogle Scholar
  7. 7.
    Lysakova, T.P., Burlov, A.S., Vlasenko, V.G., et al., Russ. J. Coord. Chem., 2016, vol. 42, p. 701.  https://doi.org/10.1134/S1070328416110075 CrossRefGoogle Scholar
  8. 8.
    Burlov, A.S., Vlasenko, V.G., Koshchienko, Y.V., et al., Russ. J. Coord. Chem., 2016, vol. 42, p. 267.  https://doi.org/10.1134/S1070328416030027 CrossRefGoogle Scholar
  9. 9.
    Burlov, A.S., Ikorskii, V.N., Nikolaevskii, S.A., et al., Russ. J. Inorg. Chem., 2008, vol. 53, no. 10, p. 1566.  https://doi.org/10.1134/S0036023608100082 CrossRefGoogle Scholar
  10. 10.
    Burlov, A.S., Vlasenko, V.G., Koshchienko, Yu.V., et al., Polyhedron, 2018, vol. 154, p. 123.  https://doi.org/10.1016/j.poly.2018.07.053 CrossRefGoogle Scholar
  11. 11.
    Burlov, A.S., Koshchienko, Yu.V., Ikorskii, V.N., et al., Russ. J. Inorg. Chem., 2006, vol. 51, no. 7, p. 1065.  https://doi.org/10.1134/S0036023606070096 CrossRefGoogle Scholar
  12. 12.
    Burlov, A.S., Uraev, A.I., Ikorskii, V.N., et al., Russ. J. Gen. Chem., 2008, vol. 78, no. 6, p. 1230.  https://doi.org/10.1134/S1070363208060224 CrossRefGoogle Scholar
  13. 13.
    Barton, J.K., Science, 1986, vol. 233, p. 727.CrossRefGoogle Scholar
  14. 14.
    Burrows, C.J. and Muller, J.G., Chem. Rev., 1998, vol. 98, p. 1109.  https://doi.org/10.1021/cr960421s CrossRefPubMedGoogle Scholar
  15. 15.
    Erkkila, K.E., Odom, D.T., and Barton, J.K., Chem. Rev., 1999, vol. 99, p. 2777.  https://doi.org/10.1021/cr9804341 CrossRefPubMedGoogle Scholar
  16. 16.
    Santini, C., Pellei, M., Gandin, V., et al., Chem. Rev., 2014, vol. 114, no. 1, p. 815.  https://doi.org/10.1021/cr400135x CrossRefPubMedGoogle Scholar
  17. 17.
    Peng Li, Mei Ju Niu, Min Hong, et al., J. Inorg. Biochem., 2014, vol. 137, p. 101.  https://doi.org/10.1016/j.jinorgbio.2014.04.005 CrossRefPubMedGoogle Scholar
  18. 18.
    Singh, K., Barwa, M.S., and Tyagi, P., Eur. J. Med. Chem., 2006, vol. 41, p. 147.  https://doi.org/10.1016/j.ejmech.2005.06.006 CrossRefPubMedGoogle Scholar
  19. 19.
    Fonkui, T.Y., Ikhile, M.I., Ndinteh, D.T., et al., Trop. J. Pharm. Res., 2018, vol. 17, p. 2507.  https://doi.org/10.4314/tjpr.v17i12.29 CrossRefGoogle Scholar
  20. 20.
    Abd El Halim, H.F., Mohamed, G.G., and Anwar, M.N., Appl. Organomet. Chem., 2018, vol. 32. https://doi.org//10.1002/aoc.3899CrossRefGoogle Scholar
  21. 21.
    Chernova, N.I., Ryabokobylko, Yu.S., Brudz’, V.G., and Bolotin, B.M., Zh. Org. Khim., 1971, vol. 7, no. 8, p. 1680.Google Scholar
  22. 22.
    Tuck, D.G., Pure Appl. Chem., 1979, vol. 51, no. 10, p. 2005.  https://doi.org/10.1351/pac197951102005 CrossRefGoogle Scholar
  23. 23.
    Chernyshov, A.A., Veligzhanin, A.A., and Zubavichus, Ya.V., Nucl. Instr. Meth. Phys. Res. A, 2009, vol. 603, p. 95.  https://doi.org/10.1016/j.nima.2008.12.167 CrossRefGoogle Scholar
  24. 24.
    Kochubei, D.I., Babanov, Yu.A., Zamaraev, K.I., et al., Rentgenospektral’nyi metod izucheniya struktury amorfnykh tel: EXAFS-spektroskopiya (X-ray Spectral Method for Investigation of Structures of Amorphous Solids: EXAFS Spectroscopy), Novosibirsk: Nauka SO, 1988.Google Scholar
  25. 25.
    Newville, M., J. Synchrotron Rad., 2001, vol. 8, p. 96. https://doi.org/10.1107/S0909049500016290 CrossRefGoogle Scholar
  26. 26.
    Zabinski, S.I., Rehr, J.J., Ankudinov, A., and Alber, R.C., Phys. Rev. B, 1995, vol. 52, p. 2995. https://doi.org/10.1103/PhysRevB.52.2995CrossRefGoogle Scholar
  27. 27.
    Lazarenko, V.A., Dorovatovskii, P.V., Zubavichus, Y.V., et al., Crystals, 2017, vol. 7, no. 11, p. 325.  https://doi.org/10.3390/cryst7110325 CrossRefGoogle Scholar
  28. 28.
    Evans, P.R., Acta Crystallogr., Sect. D: Struct. Biol., 2006, vol. 62, p. 72.  https://doi.org/10.1107/S0907444905036693 CrossRefGoogle Scholar
  29. 29.
    Battye, T.G., Kontogiannis, L., Johnson, O., et al., Acta Crystallogr., Sect. D: Struct. Biol., 2011, vol. 67, p. 271.  https://doi.org/10.1107/S0907444910048675 CrossRefGoogle Scholar
  30. 30.
    Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, no. 1, p. 112.  https://doi.org/10.1107/S0108767307043930 CrossRefGoogle Scholar
  31. 31.
    Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., et al.,  https://doi.org/10.1107/S0021889808042726 CrossRefGoogle Scholar
  32. 32.
    Kharisov, B.I., Blanco, L.M., Garnovskii, A.D., et al., Polyhedron, 1998, vol. 17, nos. 2−3, p. 381.  https://doi.org/10.1016/S0277-5387(97)00284-2 CrossRefGoogle Scholar
  33. 33.
    Kharisov, B.I., Garnovskii, D.A., Blanco, L.M., Burlov, A.S., et al., Polyhedron, 1999, vol. 18, no. 7, p. 985.  https://doi.org/10.1016/S0277-5387(98)00383-0 CrossRefGoogle Scholar
  34. 34.
    Vlasenko, V.G., Garnovskii, D.A., Aleksandrov, G.G., et al., Polyhedron, 2019, vol. 157, p. 6.  https://doi.org/10.1016/j.poly.2018.09.065 CrossRefGoogle Scholar
  35. 35.
    Garnovskii, D.A., Vlasenko, V.G., Aleksandrov, G.G., et al., Russ. J. Coord. Chem., 2018, vol. 44, p. 596.  https://doi.org/10.1134/S1070328418100032 CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • T. V. Lifintseva
    • 1
  • A. S. Burlov
    • 2
    Email author
  • V. G. Vlasenko
    • 3
  • Yu. V. Koshchienko
    • 2
  • D. A. Garnovskii
    • 4
  • S. A. Mashchenko
    • 2
  • S. I. Levchenkov
    • 1
    • 4
  • V. A. Lazarenko
    • 5
  • V. N. Khrustalev
    • 5
    • 6
  • A. L. Trigub
    • 5
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Research Institute of Physical and Organic Chemistry, Southern Federal UniversityRostov-on-DonRussia
  3. 3.Research Institute of Physics, Southern Federal UniversityRostov-on-DonRussia
  4. 4.Southern Scientific Center, Russian Academy of SciencesRostov-on-DonRussia
  5. 5.Kurchatov Institute Russian Research CenterMoscowRussia
  6. 6.Peoples Friendship UniversityMoscowRussia

Personalised recommendations