Advertisement

Russian Journal of Coordination Chemistry

, Volume 45, Issue 11, pp 824–829 | Cite as

Syntheses, Structure, and Luminescent Property of a New 2D Nd(III) Coordination Polymer Based on 4′-(4-Carboxyphenyl)-4,2′:6′,4″-Terpyridine

  • C. M. Yuan
  • X. Hu
  • F. YuanEmail author
  • Y. Li
  • X. H. Wu
  • C. S. ZhouEmail author
  • Y. T. Ai
  • Y. Liu
  • C. C. Luo
  • X. J. Qiao
  • Z. J. Li
Article
  • 5 Downloads

Abstract

A new lanthanide coordination polymer (Ln-CP) based on Nd(III), [Nd2(Cptpy)2(Glu)2(H2O)2]n · 5n(H2O) (Ι) (HCptpy = 4′-(4-carboxyphenyl)-4,2′:6′,4″-terpyridine and H2Glu = glutaric acid), have been hydrothermally synthesized and characterized by elemental analysis, IR, single crystal X-ray diffraction (CIF file CCDC no. 1857154) and thermal analyses. Single crystal X-ray analysis (CIF file CCDC no. 1857154) reveals that compound Ι displays a (4,5)-connected 2D topological net and the Schläfli symbol of (3.43.52)(32.44.52.62), which is further extended into a 3D supramolecular network by hydrogen bonds. Additionally, the near-infrared (NIR) luminescence of Ι was investigated in the solid state at room temperature.

Keywords:

neodymium terpyridine derivative luminescent property 

Notes

ACKNOWLEDGMENTS

The authors acknowledge the financial support from the Nature Science Basic Research Program of Shanxi Province (program nos. 2018JQ2039, 18JS034 and 2018JM2040), the Technology Plan Project of Shangluo (no. SK2016-44), the Natural Science Foundation of Shangluo University (no. 16SKY019) and the Undergraduate Innovation and Entrepreneurship Training Plan Projects of Shangluo University (nos. 2017086 and 201840022). The authors also thank the Fund of National Demonstration Center for Experimental Chemistry Education (Northwest University) and Shangluo Universities Key Disciplines Project, Discipline name: Chemistry.

REFERENCES

  1. 1.
    Li, J.R., Kuppler, R.J., and Zhou, H.C., Chem. Soc. Rev., 2009, vol. 38, no. 5, p. 1477.CrossRefGoogle Scholar
  2. 2.
    Chen, B., Xiang, S., and Qian, G., Acc. Chem. Res., 2010, vol. 43, no. 8, p. 1115.CrossRefGoogle Scholar
  3. 3.
    Cui, Y., Yue, Y., Qian, G., et al., Chem. Rev., 2012, vol. 112, no. 2, p. 1126.CrossRefGoogle Scholar
  4. 4.
    Corma, A., Garcia, H., and Llabrés i Xamena, F.X., Chem. Rev., 2010, vol. 110, no. 8, p. 4606.CrossRefGoogle Scholar
  5. 5.
    Liao, B.L., Lia, S.X., and Yin, Y.J., Russ. J. Coord. Chem., 2018, vol. 44, no. 1, p. 39.CrossRefGoogle Scholar
  6. 6.
    Wang, R.H., Zhou, Y.F., Sun, Y.Q., et al., Cryst. Growth Des., 2005, vol. 5, no. 1, p. 251.CrossRefGoogle Scholar
  7. 7.
    Ma, S., Yuan, D., Wang, X.S., and Zhou, H.C., Inorg. Chem., 2009, vol. 48, no. 5, p. 2072.CrossRefGoogle Scholar
  8. 8.
    Wang, Y.X., Shi, W., Li, H., et al., Chem. Sci., 2012, vol. 3, no. 12, p. 3366.CrossRefGoogle Scholar
  9. 9.
    Wen, L.L., Ke, X.H., Qiu, L., et al., Cryst. Growth Des., 2012, vol. 12, no. 8, p. 4083.CrossRefGoogle Scholar
  10. 10.
    Gai, Y.L., Jiang, F.L., Chen, L., et al., Dalton Trans., 2013, vol. 42, no. 27, p. 9954.CrossRefGoogle Scholar
  11. 11.
    Li, N.Y., Ge, Y., Wang, T., et al., CrystEngComm, 2014, vol. 16, no. 11, p. 2168.CrossRefGoogle Scholar
  12. 12.
    Zou, R.Q., Zhong, R.Q., Du, M., et al., Cryst. Growth Des., 2008, vol. 8, no. 2, p. 452.CrossRefGoogle Scholar
  13. 13.
    Ge, Y., Li, N.Y., Ji, X.Y., et al., CrystEngComm, 2014, vol. 16, no. 29, p. 6621.CrossRefGoogle Scholar
  14. 14.
    Ge, Y., Li, N.Y., Ma, W., et al., CrystEngComm, 2014, vol. 16, no. 48, p. 10949.CrossRefGoogle Scholar
  15. 15.
    Liang, X.Q., Zhou, X.H., Chen, C., et al., Cryst. Growth Des., 2009, vol. 9, no. 2, p. 1041.CrossRefGoogle Scholar
  16. 16.
    Constable, E.C., Dunphy, E.L., Housecroft, C.E., et al., Dalton Trans., 2007, no. 38, p. 4323.Google Scholar
  17. 17.
    Cooke, M.W., Tremblay, P., and Hanan, G.S., Inorg. Chim. Acta, 2008, vol. 361, no. 8, p. 2259.CrossRefGoogle Scholar
  18. 18.
    Sheldrick, G.M., SHELXS-97, Program for the Solution of Crystal Structures, Göttingen: Univ. of Göttingen, 1997.Google Scholar
  19. 19.
    Sheldrick, G.M., SHELXS-97, Program for the Refinement of Crystal Structures, Göttingen: Univ. of Göttingen, 1997.Google Scholar
  20. 20.
    Han, T., Shi, W., Niu, Z., et al., Chem. Eur. J., 2013, vol. 19, no. 3, p. 994.CrossRefGoogle Scholar
  21. 21.
    Llunell, M., Casanova, D., Cirera, J., et al., Shape 2.0, Universitat de Barcelona, 2010.Google Scholar
  22. 22.
    Litsis, O.O., Ovchynnikov, V.A., and Scherbatskii, V.P., Dalton Trans., 2015, vol. 44, no. 35, p. 15508.CrossRefGoogle Scholar
  23. 23.
    D’Vries, R.F., Gomez, G.E., Hodak, J.H., et al., Dalton Trans., 2016, vol. 45, no. 2, p. 646.CrossRefGoogle Scholar
  24. 24.
    Wang, Y.P., Li, X.Y., Li, H.H., et al., Inorg. Chem. Comm., 2016, vol. 70, p. 27.CrossRefGoogle Scholar
  25. 25.
    Janiak, C., Dalton Trans., 2003, no. 14, p. 2781.Google Scholar
  26. 26.
    Bünzli, J.C.G. and Eliseeva, S.V., J. Rare Earths, 2010, vol. 28, no. 6, p. 824.CrossRefGoogle Scholar
  27. 27.
    Sun, Y.Q., Zhang, J., Ju, Z.F., et al., Cryst. Growth Des., 2005, vol. 5, no. 5, p. 1939.CrossRefGoogle Scholar
  28. 28.
    Song, J., Liu, J., Shi, J., et al., Russ. J. Coord. Chem., 2017, vol. 43, no. 10, p. 685.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • C. M. Yuan
    • 1
  • X. Hu
    • 1
  • F. Yuan
    • 1
    Email author
  • Y. Li
    • 1
  • X. H. Wu
    • 1
  • C. S. Zhou
    • 1
    Email author
  • Y. T. Ai
    • 1
  • Y. Liu
    • 1
  • C. C. Luo
    • 1
  • X. J. Qiao
    • 1
  • Z. J. Li
    • 1
  1. 1.Shaanxi Key Laboratory of Comprehensive Utilization of Tailings Resources, College of Chemical Engineering and Modern Materials, Shangluo UniversityShangluoP.R. China

Personalised recommendations