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Russian Journal of Coordination Chemistry

, Volume 45, Issue 11, pp 759–766 | Cite as

New Heterometallic Co(III) Pivalate Complexes with 1,3-(CH2)3(NH2)2

  • I. A. LutsenkoEmail author
  • Yu. V. Nelyubina
  • P. V. Primakov
  • T. M. Ivanova
  • K. I. Maslakov
  • A. V. Khoroshilov
  • M. A. Kiskin
  • A. A. Sidorov
  • I. L. Eremenko
Article
  • 6 Downloads

Abstract

The reactions of the complex [Co(DAP)2(Piv)2] · Piv (Ia), where Piv is the pivalate anion, DAP is 1,3-diaminopropane, with Cd(II) and Li(I) pivalates afford heterometallic compounds, molecular complex [CdCo(DAP)2(Piv)5] (I) and polymeric complex [LiCo(DAP)2(Piv)4]n (II) (CIF files CCDC nos. 1908223 and 1908224, respectively). According to X-ray photoelectron spectroscopy, the electronic structure of cobalt ions in complexes Ia and I corresponds to low-spin Co(III) surrounded by strong-field ligands. The thermal destruction of I and II, studied by synchronous thermal analysis, includes stages of desorption of solvate molecules, destruction of the 1,3-diaminopropane molecule with nitrogen evolution, and degradation of carboxylate anions. The final product of thermolysis of I is the complex oxide CdCoO2.

Keywords:

heterometallic pivalate complexes cobalt(III) lithium(I) cadmium(II) crystal structure X-ray photoelectron spectroscopy synchronous thermal analysis 

Notes

ACKNOWLEDGMENTS

Single crystal and powder X-ray diffraction studies were carried out using the equipment of the Center for Molecular Structure Studies, Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences. Elemental analysis and IR spectroscopy measurements were done using the equipment of the Center for Collective Use of Physical Investigation Methods, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

FUNDING

This work was supported by the Russian Foundation for Basic Research (project no. 18-29-04043).

CONFLICT OF INTEREST

The authors declare that they have no conflicts of interest.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • I. A. Lutsenko
    • 1
    Email author
  • Yu. V. Nelyubina
    • 1
    • 2
  • P. V. Primakov
    • 2
    • 3
  • T. M. Ivanova
    • 1
  • K. I. Maslakov
    • 3
  • A. V. Khoroshilov
    • 1
  • M. A. Kiskin
    • 1
  • A. A. Sidorov
    • 1
  • I. L. Eremenko
    • 1
  1. 1.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia
  2. 2.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of SciencesMoscowRussia
  3. 3.Moscow State UniversityMoscowRussia

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