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Russian Journal of Coordination Chemistry

, Volume 45, Issue 11, pp 782–787 | Cite as

Cyclometallated Ni(II) and Pd(II) Complexes of the Azomethine Compounds: Synthesis and Structures

  • A. S. BurlovEmail author
  • S. A. Mashchenko
  • V. G. Vlasenko
  • M. A. Kiskin
  • S. A. Nikolaevskii
  • E. V. Korshunova
Article
  • 5 Downloads

Abstract

New Ni(II) and Pd(II) complexes (Ia and Ib) are synthesized on the basis of the azomethine compound 2-[(E)-[4-methyl-2-[(Z)-p-tolylazo]phenyl]iminomethyl]phenol. The structures and properties of the complexes are characterized by IR spectroscopy, 1Н NMR spectroscopy, and X-ray diffraction analysis (СIF files CCDC nos. 1899223 (Ia) and 1899224 (Ib)). The complex formation affords cyclometallated chelates. According to the X-ray diffraction data, the crystals of the Ni(II) and Pd(II) complexes are isostructural with the square geometry of the coordination mode (MCN2O, M = Ni, Pd) and formation of two five-membered and one six-membered metallocycles.

Keywords:

azo-azomethines metal complexes cyclometallation X-ray diffraction analysis 

Notes

ACKNOWLEDGMENTS

The equipment of the Center for Collective Use “Molecular Spectroscopy” was used. The X-ray diffraction studies of the NiL and PdL complexes were carried out on the equipment of the Center for Collective Use of Physical Methods of Investigation at the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences).

FUNDING

This work was supported by the Ministry of Education and Science of the Russian Federation (project no. 4.5388.2017/8.9). The X-ray diffraction studies of the NiL and PdL complexes were carried out in the framework of the state task of the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) in the area of basic research.

CONFLICT OF INTEREST

The authors declare that they have no conflicts of interest.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • A. S. Burlov
    • 1
    Email author
  • S. A. Mashchenko
    • 1
  • V. G. Vlasenko
    • 2
  • M. A. Kiskin
    • 3
  • S. A. Nikolaevskii
    • 3
  • E. V. Korshunova
    • 1
  1. 1.Research Institute of Physical and Organic Chemistry, Southern Federal UniversityRostov-on-DonRussia
  2. 2.Research Institute of Physics, Southern Federal UniversityRostov-on-DonRussia
  3. 3.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia

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