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Novel Zn and Cd Coordination Polymers Assembled from Imidazole-based Zwitterionic Ligands: Synthesis, Crystal Structures, and Luminescence Properties

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Abstract

Two transition-metal coordination polymers {[Zn2(L)2(HCOO)2]}n (I) and {[Cd2(L)3(HCOO)] ∙ 2H2O}n(II) (L = 1,3-bis(4-(methoxycarbonyl)benzyl)-1H-imidazol-3-ium anion) have been synthesized via solvo-thermal method. Both of the coordination polymers I and II were characterized by single-crystal X-ray diffraction (CIF files CCDC nos. 1834629 (I) and 1834630 (II)), FT-IR spectroscopy, elemental analysis and thermogravimetric analysis. The results shown compound I is a two dimensional sql layer structure containing interlocking structure between the left and right helix chains, and compound II is rare three dimensional six-fold interpenetrating dia topology framework. Luminescence investigations revealed that both of compound I and II emitted blue light.

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ACKNOWLEDGMENTS

This work was supported by the Natural Science Foundation of China (nos. 21671139 and 21501122), the Distinguished Professor Project of Liaoning province (2013204) and Doctoral Scientific Research Foundation of Liaoning Province (201601193 and 201601201).

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Authors and Affiliations

  1. The Key Laboratory of Inorganic Molecule-Based Chemistry of Liaoning Province, Shenyang University of Chemical Technology, 110142, Shenyang, P.R. China

    P. Yang, G. Xiong, Y. K. He, L. X. You, B. Y. Ren & Y. G. Sun

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  1. P. Yang
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  2. G. Xiong
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  3. Y. K. He
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  4. L. X. You
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  5. B. Y. Ren
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  6. Y. G. Sun
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Correspondence to G. Xiong or Y. G. Sun.

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Yang, P., Xiong, G., He, Y.K. et al. Novel Zn and Cd Coordination Polymers Assembled from Imidazole-based Zwitterionic Ligands: Synthesis, Crystal Structures, and Luminescence Properties. Russ J Coord Chem 45, 741–747 (2019). https://doi.org/10.1134/S1070328419100087

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  • DOI: https://doi.org/10.1134/S1070328419100087

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