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Russian Journal of Coordination Chemistry

, Volume 45, Issue 1, pp 22–29 | Cite as

Pseudo-Polymeric Mercury(II) Morpholinedithiocarbamate [Hg{S2CN(CH2)4O}2]n: Supramolecular Structure (a Role of Secondary Hg···S Bonds), 13C and 15N CP-MAS NMR Spectra, and Thermal Behavior

  • O. V. Loseva
  • T. A. Rodina
  • A. V. IvanovEmail author
Article
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Abstract

A new representative of mercury(II) dithiocarbamate complexes, crystalline bis(morpholinedithiocarbamato-S,S')mercury(II) with the pseudo-1D-polymeric structure, is preparatively synthesized. The structure is characterized by 13С and 15N MAS NMR spectroscopy and X-ray diffraction analysis (CIF file CCDC no. 1821609). Pairs of symmetric secondary Hg⋅⋅⋅S bonds (3.400 Å) combine mononuclear [Hg{S2CN(CH2)4O}2] molecules, including planar polygons [HgS4], into a linear pseudo-polymeric chain. The study of the thermal behavior shows that the two-stage mass loss detected by thermogravimetry is due to the thermal destruction of the complex with the formation of HgS and its subsequent sublimation.

Keywords:

mercury(II) alkylenedithiocarbamates structural organization secondary bonds Hg⋅⋅⋅S X-ray diffraction analysis multinuclear (1315N) MAS NMR spectroscopy simultaneous thermal analysis 

Notes

ACKNOWLEDGMENTS

The authors are grateful to Prof. O.N. Antsutkin and Dr. V. Gowda (Luleå University of Technology, Sweden) for the kindly presented possibility and help in recording 13С and 15N MAS NMR spectra.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  1. 1.Institute of Geology and Nature Management, Far East Branch, Russian Academy of SciencesBlagoveshchenskRussia
  2. 2.Amur State UniversityBlagoveshchenskRussia

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