Advertisement

Russian Journal of Coordination Chemistry

, Volume 44, Issue 11, pp 673–677 | Cite as

Mononuclear Molybdenum Oxohalide Complexes (Bu4N)[MoOCl4(H2O)] and (Bu4N)[MoOBr4(H2O)]: Synthesis and Crystal Structures

  • S. A. Adonin
  • L. I. Udalova
  • P. A. Abramov
  • M. N. Sokolov
  • V. P. Fedin
Article
  • 68 Downloads

Abstract

The oxidation of K3[MoCl6] with air oxygen in aqueous solutions of HX (X = Cl, Br) in the presence of n-tetrabutylammonium salts affords mononuclear heteroligand complexes (Bu4N)[MoOCl4(H2O)] (I) and (Bu4N)[MoOBr4(H2O)] (II). The complexes are characterized by X-ray diffraction analysis (СIF files CCDC nos. 1812657 (I) and 1812658 (II).

Keywords:

molybdenum halide complexes heteroligand complexes X-ray diffraction analysis 

Notes

REFERENCES

  1. 1.
    Stewart, D.F. and O’Donnell, T.A., Science, 1966, vol. 210, p. 836.Google Scholar
  2. 2.
    Johnston, D.H., Stern, C.L., and Shriver, D.F., Inorg. Chem., 1993, vol. 32, p. 5170.CrossRefGoogle Scholar
  3. 3.
    Ramirez-Tagle, R. and Arratia-Perez, R., Chem. Phys. Lett., 2009, vol. 45, p. 232.CrossRefGoogle Scholar
  4. 4.
    Bain, R.L., Shriver, D.F., and Ellis, D.E., Inorg. Chim. Acta, 2001, vol. 325, р. 171.Google Scholar
  5. 5.
    Bartalucci, N., Bortoluzzi, M., Marchetti, F., et al., New J. Chem., 2017, vol. 41, p. 4329.CrossRefGoogle Scholar
  6. 6.
    Cotton, F.A. and Vidyasagar, F., Polyhedron, 1995, vol. 14, p. 3077.CrossRefGoogle Scholar
  7. 7.
    Kazin, P.E., Bel’skii, V.K., Zhirov, A.I., et al., Russ. J. Inorg. Chem., 1985, vol. 30, p. 1426.Google Scholar
  8. 8.
    Spitsyn, V.I., Kazin, P.E., Felin, M.G., et al., Russ. J. Inorg. Chem., 1987, vol. 32, p. 2392.Google Scholar
  9. 9.
    Herbowski, A. and Lis, T., Polyhedron, 1985, vol. 4, p. 127.CrossRefGoogle Scholar
  10. 10.
    Fettinger, J.C., Gordon, J.C., Mattamana, S.P., et al., Inorg. Chem., 1996, vol. 35, p. 7404.CrossRefPubMedGoogle Scholar
  11. 11.
    Atwood, J.L. and Junk, P.C., J. Coord. Chem., 2000, vol. 51, p. 379.CrossRefGoogle Scholar
  12. 12.
    Spitsin, V.I., Kazin, P.E., Subbotin, M.Yu., et al., Dokl. Akad. Nauk SSSR, 1986, vol. 287, p. 134.Google Scholar
  13. 13.
    Sevastianiova, T.N., Davydova, E.I., Kazakov, I.V., et al., Russ. Chem. Bull., 2015, vol. 64, p. 2523.CrossRefGoogle Scholar
  14. 14.
    Torubaev, Y., Pasynskii, A., and Mathur, P., Coord. Chem. Rev., 2012, vol. 256, p. 709.CrossRefGoogle Scholar
  15. 15.
    Davydova, E.I., Sevastianova, T.N., Suvorov, A.V., et al., Coord. Chem. Rev., 2010, vol. 254, p. 2031.CrossRefGoogle Scholar
  16. 16.
    Handbuch der Präparativen Inorganische Chemie, Brauer, G., Ed., Stuttgart: Ferdidand Enke, 1981, vol. 5.Google Scholar
  17. 17.
    CrysAlisPro. Agilent Technologies. Version 1.171.37.35 (release 13-08-2014 CrysAlis171. NET).Google Scholar
  18. 18.
    Sheldrick, G.M., Acta Crystallogr., Sect C: Struct. Chem., 2015, vol. 71, p. 3.CrossRefGoogle Scholar
  19. 19.
    Hübschle, C.B., Sheldrick, G.M., Dittrich, B., J. Appl. Crystallogr., 2011, vol. 44, p. 1281.CrossRefPubMedPubMedCentralGoogle Scholar
  20. 20.
    Gordon, J.C., Mattamana, S.P., and Poli, R., Polyhedron, 1995, vol. 14, p. 1339.CrossRefGoogle Scholar
  21. 21.
    Bino, A. and Cotton, F.A., Inorg. Chem., 1979, vol. 18, p. 2710.CrossRefGoogle Scholar
  22. 22.
    Wu, C.-D., Zhang, Q.-Z., Lu, C.-Z., et al., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2001, vol. 57, p. m511.CrossRefGoogle Scholar
  23. 23.
    Chivu, H., Braun, B., Micu, O., et al., Rev. Chim., 2011, vol. 62, p. 283.Google Scholar
  24. 24.
    Honzicek, J., Mukhopadhay, A., Santos-Silva, T., et al., Organometallics, 2009, vol. 28, p. 2871.CrossRefGoogle Scholar
  25. 25.
    Sergienko, V.S., Minacheva, L.K., Sagikov, G.G., et al., Russ. J. Inorg. Chem., 1992, vol. 37, p. 346.Google Scholar
  26. 26.
    Neumann, R. and Assael, I., J. Chem. Soc., Chem. Commun., 1989, p. 547.Google Scholar
  27. 27.
    Scane, J.G., Acta Crystallogr., 1967, vol. 23, p. 85.CrossRefGoogle Scholar
  28. 28.
    Mohammed, A.K., Fronczek, F.R., and Maverick, A.W., Inorg. Chim. Acta., 1994, vol. 226, p. 25.CrossRefGoogle Scholar
  29. 29.
    Fettinger, J.C., Mattamana, S.P., and Poli, R., Acta Crystallpgr., Sect. C: Cryst. Struct. Commun., 1998, vol. 54, p. 184.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • S. A. Adonin
    • 1
    • 2
  • L. I. Udalova
    • 2
  • P. A. Abramov
    • 1
    • 2
  • M. N. Sokolov
    • 1
    • 3
  • V. P. Fedin
    • 1
    • 2
  1. 1.Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of SciencesNovosibirskRussia
  2. 2.Novosibirsk State UniversityNovosibirskRussia
  3. 3.Kazan (Volga Region) Federal UniversityKazanRussia

Personalised recommendations