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Russian Journal of Coordination Chemistry

, Volume 44, Issue 10, pp 585–588 | Cite as

Unusual Bridging Coordination Modes of THF and Piv Anions in the Hexanuclear Nickel(II) Carboxylate Complex

  • N. V. Gogoleva
  • G. G. Aleksandrov
  • M. A. Kiskin
  • A. A. Sidorov
  • I. L. Eremenko
Article

Abstract

The recrystallization of complex [Ni9(OH)6(Piv)12(HPiv)4] (Piv is anion of trimethylacetic acid) from a THF–MeCN (6 : 1) mixture gives a new hexanuclear compound of nickel(II): [Ni63-OH)2(Piv)10(THF)4]. Its structure (CIF file CCDC no. 1579976) exhibits rare examples of coordination of the µ2-THF and µ4-Piv ligands.

Keywords:

nickel(II) carboxylate complexes structure 

Notes

ACKNOWLEDGMENTS

Physicochemical studies were carried out on the equipment of the Center for Collective Use at the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences. This work was supported by the Russian Academy of Sciences and the Federal Agency of Scientific Organizations.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • N. V. Gogoleva
    • 1
  • G. G. Aleksandrov
    • 1
  • M. A. Kiskin
    • 1
  • A. A. Sidorov
    • 1
  • I. L. Eremenko
    • 1
    • 2
  1. 1.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia
  2. 2.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of SciencesMoscowRussia

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