Russian Journal of Coordination Chemistry

, Volume 44, Issue 10, pp 585–588 | Cite as

Unusual Bridging Coordination Modes of THF and Piv Anions in the Hexanuclear Nickel(II) Carboxylate Complex

  • N. V. Gogoleva
  • G. G. Aleksandrov
  • M. A. Kiskin
  • A. A. Sidorov
  • I. L. Eremenko


The recrystallization of complex [Ni9(OH)6(Piv)12(HPiv)4] (Piv is anion of trimethylacetic acid) from a THF–MeCN (6 : 1) mixture gives a new hexanuclear compound of nickel(II): [Ni63-OH)2(Piv)10(THF)4]. Its structure (CIF file CCDC no. 1579976) exhibits rare examples of coordination of the µ2-THF and µ4-Piv ligands.


nickel(II) carboxylate complexes structure 



Physicochemical studies were carried out on the equipment of the Center for Collective Use at the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences. This work was supported by the Russian Academy of Sciences and the Federal Agency of Scientific Organizations.


  1. 1.
    Kiskin, M.A. and Eremenko, I.L., Usp. Khim., 2006, vol. 75, p. 627.CrossRefGoogle Scholar
  2. 2.
    Lin, Z., Wragg, D.S., Warren, J.E., and Morris, R.E., J. Am. Chem. Soc., 2007, vol. 129, p. 10334.CrossRefGoogle Scholar
  3. 3.
    Forster, P.M., Yang, Z., and Cheetham, A.K., Solid State Sci., 2003, vol. 5, p. 635.CrossRefGoogle Scholar
  4. 4.
    Weber, B., Betz, R., Bauer, W., and Schlamp, S., Z. Anorg. Allg. Chem., 2011, vol. 637, p. 102.CrossRefGoogle Scholar
  5. 5.
    Kiskin, M.A., Fomina, I.G., Aleksandrov, G.G., et al., Inorg. Chem. Commun., 2004, vol. 8, p. 89.CrossRefGoogle Scholar
  6. 6.
    Fomina, I.G., Aleksandrov, G.G., Dobrokhotova, Zh.V., et al., Izv. Akad. Nauk, Ser. Khim., 2006, no. 11, p. 1841.Google Scholar
  7. 7.
    Eremenko, I.L., Kiskin, M.A., Fomina, I.G., et al., J. Cluster Sci., 2005, vol. 16, p. 331.CrossRefGoogle Scholar
  8. 8.
    Eremenko, I.L., Nefedov, S.E., Sidorov, A.A., et al., Inorg. Chem., 1999, vol. 38, p. 3764.CrossRefGoogle Scholar
  9. 9.
    Eremenko, I.L., Golubnichaya, M.A., Nefedov, S.E., et al., Izv. Akad. Nauk, Ser. Khim., 1999, no. 4, p. 725.Google Scholar
  10. 10.
    Eremenko, I.L., Nefedov, S.E., Sidorov, A.A., and Moiseev, I.I., Izv. Akad. Nauk, Ser. Khim., 1999, no. 2, p. 409.Google Scholar
  11. 11.
    Ovcharenko, V., Fursova, E., Romanenko, G., et al., Inorg. Chem., 2006, vol. 45, p. 5338.CrossRefGoogle Scholar
  12. 12.
    Sidorov, A.A., Fomina, I.G., Talismanov, S.S., et al., Russ. J. Coord. Chem., 2001, vol. 27, no. 8, p. 548.CrossRefGoogle Scholar
  13. 13.
    Sheldrick, G.M., SADABS. Program for Scanning and Correction of Area Detector Data, Göttinngen: Univ. of Göttingen, 2004.Google Scholar
  14. 14.
    Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, no. 1, p. 112.CrossRefGoogle Scholar
  15. 15.
    Weber, B., Betz, R., Bauer, W., and Schlamp, S., Z. Anorg. Allg. Chem., 2011, vol. 637, p. 102.CrossRefGoogle Scholar
  16. 16.
    Déniz, M., Hernández-Rodríguez, I., Pasán, J., et al., CrystEngComm, 2014, vol. 16, p. 2766.CrossRefGoogle Scholar
  17. 17.
    Chen, Z., Quan, L., Liu, L., et al., Eur. J. Inorg. Chem., 2015, p. 1463.Google Scholar
  18. 18.
    Kuhlman, R., Schimek, G.L., and Kolis, J.W., Inorg. Chem., 1999, vol. 38, p. 194.CrossRefGoogle Scholar
  19. 19.
    Fursova, E., Kuznetsova, O., Ovcharenko, V., et al., Polyhedron, 2007, vol. 26, p. 2079.CrossRefGoogle Scholar
  20. 20.
    Kuznetsova, O.V., Fursova, E.Yu., and Ovcharenko, V.I., Izv. Akad. Nauk, Ser. Khim., 2008, no. 10, p. 2156.Google Scholar
  21. 21.
    Mikuriya, M., Azuma, H., and Handa, M., Mol. Cryst. Liq. Cryst., 2002, vol. 379, p. 205.CrossRefGoogle Scholar
  22. 22.
    Wenga, C.-H., Chenga, S.-C., Wei, H.-M., et al., Inorg. Chim. Acta, 2006, vol. 359, p. 2029.CrossRefGoogle Scholar
  23. 23.
    Pang, Y. and Zheng, Y., Chin. J. Chem., 2015, vol. 33, p. 1347.CrossRefGoogle Scholar
  24. 24.
    Herzog, A., Liu, F.-Q., Roesky, H.W., et al., Organometallics, 1994, vol. 13, p. 1251.CrossRefGoogle Scholar
  25. 25.
    Duan, X.E., Yuan, S.F., Tong, H.B., et al., Dalton Trans., 2012, vol. 21, p. 9460.CrossRefGoogle Scholar
  26. 26.
    Burkovskaya, N.P., Nikiforova, M.E., Kiskin, M.A., et al., Polyhedron, 2011, vol. 30, p. 2941.CrossRefGoogle Scholar
  27. 27.
    Crescenzi, R., Solari, E., Floriani, C., et al., Inorg. Chem., 1996, vol. 35, p. 2413.CrossRefGoogle Scholar
  28. 28.
    Snyder, C.J., Heeg, M.J., and Winter, C.H., Inorg. Chem., 2011, vol. 50, p. 9210.CrossRefGoogle Scholar
  29. 29.
    Duan, X.-E., Yuan, S.-F., Tong, H.-B., et al., Dalton Trans., 2012, vol. 41, p. 9460.CrossRefGoogle Scholar
  30. 30.
    Baxter, C.W., Higgs, T.C., Bailey, P.J., et al., Chem.-Eur. J., 2006, vol. 12, p. 6166.CrossRefGoogle Scholar
  31. 31.
    Anson, C.E., Langer, R., Ponikiewski, L., and Rothenberger, A., Inorg. Chim. Acta, 2005, vol. 358, p. 3967.CrossRefGoogle Scholar
  32. 32.
    Koerner, R., Olmstead, M.M., Ozarowski, A., and Balch, A.L., Inorg. Chem., 1999, vol. 38, p. 3262.CrossRefGoogle Scholar
  33. 33.
    Komorski, S., Leszczyn'ski, M.K., Justyniak, I., and Lewi'nski, J., Inorg. Chem., 2016, vol. 55, p. 5104.CrossRefGoogle Scholar
  34. 34.
    Anantharaman, G., Chandrasekhar, V., Walawalkar, M.G., et al., Dalton Trans., 2004, p. 1271.Google Scholar
  35. 35.
    Bury, W., Justyniak, I., Prochowicz, D., et al., Chem. Commun., 2012, vol. 48, p. 7362.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • N. V. Gogoleva
    • 1
  • G. G. Aleksandrov
    • 1
  • M. A. Kiskin
    • 1
  • A. A. Sidorov
    • 1
  • I. L. Eremenko
    • 1
    • 2
  1. 1.Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesMoscowRussia
  2. 2.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of SciencesMoscowRussia

Personalised recommendations