Russian Journal of Coordination Chemistry

, Volume 41, Issue 9, pp 585–591 | Cite as

Reactivity of two MeCp-cobalt complexes containing 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolate (S2C2B10H10)2– units toward alkynes

  • H. D. Ye
  • J. R. Hu
  • H. N. Peng
  • J. L. Xie
  • Q. Ye
  • Y. H. Li
  • Z. S. Xing
Article

Abstract

Treatment of o-carborane, n-butyllithium, sulfur, and MeCpCo(CO)I2 under argon leads to twoMeCp-cobalt complexes MeCpCoS2C2B10H10 (I) and (MeCp)2Co2S2C2B10H10 (II). Complex I reacts with phenylacetylene or dimethyl acetylene dicarboxylate to afford B–H activitied complex (MeCpCoS2C2B10H9)(Ph–C–CH2) (III) and addition complex (MeCpCoS2C2B10H10)(MeO2C–C=C–CO2Me) (IV), respectively. Complex II reacts neither with phenylacetylene nor with dimethyl acetylene dicarboxylate. Complexes IIIV have been characterized by elemental analysis, mass, NMR spectroscopy, IR, and X-ray structural analyses (CIF files CCDC nos. 1045892 (II), 1045893 (III) and 1045894 (IV)).

Keywords

Boron Neutron Capture Therapy Phenylacetylene Cobalt Atom Solid State Structure Dimethyl Acetylene Dicarboxylate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Pleek, J., Chem. Rev., 1992, vol. 92, no. 2, p. 269.CrossRefGoogle Scholar
  2. 2.
    Grimes, R.N., Chem. Rev., 1992, vol. 92, no. 2, p. 251.CrossRefGoogle Scholar
  3. 3.
    Deng, L. and Xie, Z.W., Coord. Chem. Rev., 2007, vol. 251, nos. 17–20, p. 2452.CrossRefGoogle Scholar
  4. 4.
    Bregadze, V.I., Chem. Rev., 1992, vol. 92, no. 2, p. 209.CrossRefGoogle Scholar
  5. 5.
    Larsen, A.S., Holbrey, J.D., Tham, F.S., et al., J. Am. Chem. Soc., 2000, vol. 122, no. 30, p. 7264.CrossRefGoogle Scholar
  6. 6.
    Hawthorne, M.F. and Maderna, A., Chem. Rev., 1999, vol. 99, no. 12, p. 3421.CrossRefGoogle Scholar
  7. 7.
    Ivanova, S.M., Ivanov, S.V., Miller, S.M., et al., Inorg. Chem., 1999, vol. 38, no. 17, p. 3756.CrossRefGoogle Scholar
  8. 8.
    Westerhausen, M., Gückel, C., Schneiderbauer, S., et al., Angew. Chem. Int. Ed., 2001, vol. 40, no. 10, p. 1902.CrossRefGoogle Scholar
  9. 9.
    Fox, M.A. and Hughes, A.K., Coord. Chem. Rev., 2004, vol. 248, nos. 5–6, p. 457.CrossRefGoogle Scholar
  10. 10.
    Valliant, J.F., Guenther, K.J., and King, A.S., Coord. Chem. Rev., 2002, vol. 232, nos. 1–2, p. 173.CrossRefGoogle Scholar
  11. 11.
    Jin, G.X., Wang, J.Q., Zhang, C., et al., Angew. Chem. Int. Ed., 2005, vol. 44, no. 2, p. 259.CrossRefGoogle Scholar
  12. 12.
    Meng, X., Wang, F., and Jin, G.X., Coord. Chem. Rev., 2010, vol. 254, nos. 11–12, p. 1260.CrossRefGoogle Scholar
  13. 13.
    Wang, J.Q, Ren, C.X., Weng, L.H., et al., Chem. Commun., 2006, no. 2, p. 162.CrossRefGoogle Scholar
  14. 14.
    Zhang, R., Zhu, L., Liu, G.F., et al., J. Am. Chem. Soc., 2012, vol. 134, no. 25, p. 10341.CrossRefGoogle Scholar
  15. 15.
    Xu, B.H., Wu, D.H., Li, Y.Z., et al., Organometallics, 2007, vol. 26, no. 17, p. 4344.CrossRefGoogle Scholar
  16. 16.
    Won, J.H., Kim, D.H., Kim, B.Y., et al., Organometallics, 2002, vol. 21, no. 7, p. 1443.CrossRefGoogle Scholar
  17. 17.
    Hu, J.R., Ye, H.D., Wang, Y.H., et al., Russ. J. Coord. Chem., 2014, vol. 40, no. 6, p. 413.CrossRefGoogle Scholar
  18. 18.
    Ye, H.D., Xu, B.H., Xie, M.S., et al., Dalton Trans., 2011, vol. 40, no. 24, p. 6541.CrossRefGoogle Scholar
  19. 19.
    Li, Y.G., Jiang, Q.B., Li, Y.Z., et al., Inorg. Chem., 2010, vol. 49, no. 12, p. 5584.CrossRefGoogle Scholar
  20. 20.
    Hu, J.R., Liu, G.F., Jiang, Q.B., et al., Inorg. Chem., 2010, vol. 49, no. 23, p. 11199.CrossRefGoogle Scholar
  21. 21.
    Xu, B.H., Peng, X.Q., Xu, Z.W., et al., Inorg. Chem., 2008, vol. 47, no. 17, p. 7928.CrossRefGoogle Scholar
  22. 22.
    Kim, D.H., Ko, J., Park, K., et al., Organometallics, 1999, vol. 18, no. 15, p. 2738.CrossRefGoogle Scholar
  23. 23.
    Sheldrick, G.M., SHELXS-97, Program for the Solution of Crystal Structures, Göttingen (Germany): Univ. of Göttingen, 1997.Google Scholar
  24. 24.
    Sheldrick, G.M., SHELXL-97, Program for the Refinement of Crystal Structures, Göttingen (Germany): Univ. of Göttingen, 1997.Google Scholar
  25. 25.
    Xu, B.H., Peng, X.Q., Li, Y.Z., et al., Chem. Eur. J., 2008, vol. 14, no. 30, p. 9347.CrossRefGoogle Scholar
  26. 26.
    Ye, H.D., Ding, G.Y., Xie, M.S., et al., Dalton Trans., 2011, vol. 40, no. 10, p. 2306.CrossRefGoogle Scholar
  27. 27.
    Ye, H.D., Bai, W.J., Xie, M.S., et al., Eur. J. Inorg. Chem., 2011, vol. 2011, no. 17, p. 2763.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • H. D. Ye
    • 1
  • J. R. Hu
    • 1
  • H. N. Peng
    • 1
  • J. L. Xie
    • 1
  • Q. Ye
    • 1
  • Y. H. Li
    • 1
  • Z. S. Xing
    • 1
  1. 1.Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical EngineeringShangrao Normal UniversityJiangxiP.R. China

Personalised recommendations