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Russian Journal of Coordination Chemistry

, Volume 41, Issue 6, pp 405–409 | Cite as

Synthesis, structural characterization, and properties of a Cd(II) complex with a carboxylate- and benzimidazolyl-containing ligand

  • C. H. Dai
  • F. L. Mao
Article
  • 57 Downloads

Abstract

The hydrothermal reaction of cadmium salt with 3,5-bis(benzimidazol-1-ylmethyl)benzoic acid (HL) forms a new complex [Cd(L)2] · 3H2O (I). This complex has been characterized by single-crystal X-ray diffraction, IR, elemental and thermogravimetric analyses and shows 3D flu framework structure with 2-nodal (3,6)-connected (42.6)2(44.62.89) topology. Luminescent property of I was investigated. Moreover, single crystals of HL were obtained accidentally in the hydrothermal reaction of the HL with MnSO4 at 160°C, and its crystal structure has been characterized by single-crystal X-ray diffraction (CIF files CCDC nos. 1020274 (HL) and 1020275 (I)).

Keywords

Benzoic Acid Coordination Chemistry Coordination Polymer Benzimidazolyl Isophthalic Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  1. 1.School of Chemistry and Chemical EngineeringYancheng Teachers UniversityYanchengP.R. China

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