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Russian Journal of Coordination Chemistry

, Volume 40, Issue 4, pp 232–239 | Cite as

Syntheses and crystal structures of two coordination polymer based on 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene

  • G. X. LiuEmail author
  • Z. Q. Liu
Article
  • 62 Downloads

Abstract

Two novel coordination polymers, [Zn2(CAM)2(Titmb)] (I) and [Zn4Co(OH)2(BTEC)2 (Titmb)2(H2O)2] · 2H2O (II) (H2CAM = camphor acid, H4BTEC = 1,2,4,5-benzenetetracarboxylic acid, and Titmb = 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene), have been hydrothermal prepared and characterized by IR spectroscopy, elemental analysis, and single-crystal X-ray diffraction. Complex I displays an unusual three-dimensional (3,4,6)-connected network with (4.64.8)2(42.64.89)(62.8)2 topology. Complex II exhibits an interesting heterometallic 3D metal-organic framework. Moreover, the luminescent properties of I have been investigated in the solid state at room temperature.

Keywords

Coordination Chemistry Coordination Polymer Carboxylate Oxygen Atom Double Chain Flexible Ligand 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  1. 1.School of Biochemical and Environmental EngineeringNanjing Xiaozhuang UniversityNanjingP.R. China
  2. 2.School of Chemistry and Chemical EngineeringAnqing Normal UniversityAnqingP.R. China

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