Russian Journal of Coordination Chemistry

, Volume 37, Issue 7, pp 552–555 | Cite as

Crystal structure and magnetic properties of the binuclear copper(II) complex based on 1,3-diaminopropan-2-ol N,N′-bis(3-formyl-5-tert-butylsalicylidene)

  • Yu. P. Tupolova
  • L. D. Popov
  • S. I. LevchenkovEmail author
  • I. N. Shcherbakov
  • K. Yu. Suponitskii
  • A. M. Ionov
  • V. A. Kogan


1,3-Diaminopropan-2-ol N,N′-bis(3-formyl-5-tert-butylsalicylidene) (H3L) and the binuclear copper(II) complex based on H3L, [Cu2L(CH3COO)] (I), are synthesized. The compounds are studied by IR and 1H NMR spectroscopies, magnetochemistry, and X-ray diffraction analysis. Compared to the copper(II) complexes with 1,3-diaminopropan-2-ol N,N′-bis(salicylidene), complex I is characterized by a substantial change in the structure resulting in weakening of the antiferromagnetic exchange interaction.


DMSO Molecule Formyl Group Salicylidene Binuclear Copper Antiferromagnetic Exchange Interaction 
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Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • Yu. P. Tupolova
    • 1
  • L. D. Popov
    • 1
  • S. I. Levchenkov
    • 2
    Email author
  • I. N. Shcherbakov
    • 1
  • K. Yu. Suponitskii
    • 3
  • A. M. Ionov
    • 1
  • V. A. Kogan
    • 1
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Research CenterRussian Academy of SciencesRostov-on-DonRussia
  3. 3.Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia

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