Russian Journal of Coordination Chemistry

, Volume 37, Issue 7, pp 483–491 | Cite as

Transition metal complexes with 2-(N-tosylamino)benzaldehyde 1-phthalazinylhydrazone

  • L. D. Popov
  • I. N. Shcherbakov
  • S. I. Levchenkov
  • Yu. P. Tupolova
  • A. S. Burlov
  • G. G. Aleksandrov
  • V. V. Lukov
  • V. A. Kogan
Article

Abstract

2-(N-Tosylamino)benzaldehyde 1-phthalazinylhydrazone (H2L) and its complexes with Cu(II), Ni(II), and Mn(II) were obtained. The acid-basic properties of the hydrazone were studied using potentiometry and spectrophotometry. The experimental data were compared with the results of quantum-chemical DFT calculations. The structure of the binuclear complex [Cu2L2] was determined using X-ray diffraction. The broken symmetry approach was used to calculate the exchange coupling constant of the copper ions.

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Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • L. D. Popov
    • 1
  • I. N. Shcherbakov
    • 1
  • S. I. Levchenkov
    • 2
  • Yu. P. Tupolova
    • 1
  • A. S. Burlov
    • 1
  • G. G. Aleksandrov
    • 3
  • V. V. Lukov
    • 1
  • V. A. Kogan
    • 1
  1. 1.Southern Federal UniversityRostov-on-DonRussia
  2. 2.Southern Scientific CenterRussian Academy of SciencesRostov-on-DonRussia
  3. 3.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia

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