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Hydrothermal synthesis and crystal structure of a new 3D Co(II) supramolecule bearing 2-propylimidazole-4,5-dicarboxylate

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Abstract

A new supramolecule [Co(H2PIDC)2(H2O)2] · 3H2O (I) (H2PIDC− is singly deprotonated 2-propylimidazole-4,5-dicarboxylate) has been synthesized and characterized by the X-ray diffraction method. Compound I crystallizes in the tetragonal space group I41/acd with the cell parameters a = 22.1665(14), c = 18.538(2) Å, M r = 543.35, V = 9108.7(14) Å3, ρ c = 1.585 g/cm3, Z = 16, F(000) = 4528. The Co2+ ion is coordinated by two N-O chelated H2PIDC− ligands and two water oxygen atoms to form a distorted octahedral geometry. The mononuclear complexes are linked by a hydrogen bond into 1D w-shaped double-chain fragments, which are then linked by oxygen-bifurcated acceptor hydrogen bonds into a 3D framework.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, 471022, P.R. China

    X. F. Liu, L. F. Ma & L. Y. Wang

  2. School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, P.R. China

    X. F. Liu

Authors
  1. X. F. Liu
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  2. L. F. Ma
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  3. L. Y. Wang
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Correspondence to L. Y. Wang.

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Liu, X.F., Ma, L.F. & Wang, L.Y. Hydrothermal synthesis and crystal structure of a new 3D Co(II) supramolecule bearing 2-propylimidazole-4,5-dicarboxylate. Russ J Coord Chem 36, 680–684 (2010). https://doi.org/10.1134/S1070328410090071

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  • DOI: https://doi.org/10.1134/S1070328410090071

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