Russian Journal of Coordination Chemistry

, Volume 33, Issue 11, pp 809–814 | Cite as

Synthesis and crystal structure of the π copper(I) cyanide complex with N,N′-diallyl thiocarbamide 2CuCN · (C3H5NH)2CS

  • A. A. Vakulka
  • Ya. E. Filinchuk
  • M. G. Mys’kiv
Article

Abstract

Crystals of the π copper(I) cyanide complex with N,N′-diallyl thiocarbamide, 2CuCN · (C3H5NH)2CS (I), are synthesized from an aqueous-methanol solution of potassium nitroprusside, diallyl thiocarbamide on a copper electrode using the method of alternating-current electrochemical synthesis. The crystals are monoclinic: space group P21/n, a = 6.9440(5) Å, b = 13.760(1)) Å, c = 12.733(1) Å, β = 97.280(9)°, V = 1206.8(2) Å3, Z = 4, R = 0.0361, Rw = 0.0362 for 2836 independent reflections with F ≥ 4σ(F). A unique polymeric structure is built due to the Cu(I)-(C=C) π bond and the bridging function of the thioamide S atom of the ligand molecule and one of the two independent cyano groups.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Filinchuk, Ya.E., Shollmeier, D., Oliinik, V.V., et al., Koord. Khim., 1996, vol. 22, no. 11, p. 870 [Russ. J. Coord. Chem. (Engl. Transl.), vol. 22, no. 11, p. 815].Google Scholar
  2. 2.
    Oliinik, V.V., Goreshnik, E.A., Shollmeier, D., and Mys’kiv, M.G., Koord. Khim., 1997, vol. 23, no. 7, p. 548 [Russ. J. Coord. Chem. (Engl. Transl.), vol. 23, no. 7, p.511].Google Scholar
  3. 3.
    Filinchuk, Ya.E., Oliinik, V.V., Glowiak, T., and Mys’kiv, M.G., Koord. Khim., 2001, vol. 27, no. 2, p. 139 [Russ. J. Coord. Chem. (Engl. Transl.), vol. 27, no. 2, p. 126].Google Scholar
  4. 4.
    Filinchuk, Ya.E., Oliinik, V.V., and Shollmeier, D., Koord. Khim., 1999, vol. 25, no. 3, p. 226 [Russ. J. Coord. Chem. (Engl. Transl.), vol. 25, no. 3, p. 209].Google Scholar
  5. 5.
    Stocker, F.B., Troester, M.A., and Britton, D., J. Chem. Crystallogr., 2006, vol. 30, no. 6, p. 389.CrossRefGoogle Scholar
  6. 6.
    Heller, M. and Scheldrick, W.S., Z. Anorg. Allg. Chem., 2001, vol. 627, no. 4, p. 569.CrossRefGoogle Scholar
  7. 7.
    Chesnut, D.J., Plewak, D., and Zubieta, J., Dalton Trans., 2001, no. 18, p. 2567.Google Scholar
  8. 8.
    Weygand, C. and Hilgetag, G., Organisch-Chemische Experimentierkunst (Experimental Methods in Organic Chemistry), Leipzig: Johann Ambrosius Barth, 1964.Google Scholar
  9. 9.
    Myhkalichko, B.M. and Mys’kiv, M.G., Ukr. Patent no. 25450, Byull. Izobret., 1998, no. 6.Google Scholar
  10. 10.
    Olbrich, F., Kopf, J., and Weiss, E., J. Organomet. Chem., 1993, vol. 456, no. 2, p. 293.CrossRefGoogle Scholar
  11. 11.
    Mys’kiv, M.G. and Oliinik, V.V., Koord. Khim., 1995, vol. 21, no. 4, p. 290.Google Scholar
  12. 12.
    Colacio, E., Domingues-Vera, J.M., Lloret, F., et al., Inorg. Chem., 2003, vol. 42, no. 13, p. 4209.CrossRefGoogle Scholar
  13. 13.
    Desiraju, G., Dalton Trans., 2000, no. 21, p. 3745.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2007

Authors and Affiliations

  • A. A. Vakulka
    • 1
  • Ya. E. Filinchuk
    • 2
  • M. G. Mys’kiv
    • 1
  1. 1.Franko State UniversityLvivUkraine
  2. 2.University of GenevaGeneve 4Switzerland

Personalised recommendations