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Russian Journal of Coordination Chemistry

, Volume 32, Issue 8, pp 545–551 | Cite as

Interpretation of the IR spectra of aluminum, gallium, and indium tris(acetylacetonates)

  • S. N. Slabzhennikov
  • O. B. Ryabchenko
  • L. A. Kuarton
Article

Abstract

The IR spectra of M(Acac)3 (M = Al, Ga, and In; Acac−1 is the acetylacetonate ion) and their isotope-substituted analogs were calculated by the Hartree-Fock-Roothaan method. The results obtained and available literature data were used to assign the absorption bands. A correlation was found between the force constants of the M-O bond and the stability constants of the complexes M(Acac)3.

Keywords

Acac Stability Constant Force Constant Coordination Chemistry Molecular Complex 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Inc. 2006

Authors and Affiliations

  • S. N. Slabzhennikov
    • 1
  • O. B. Ryabchenko
    • 1
  • L. A. Kuarton
    • 1
  1. 1.Institute of Physics and Information TechnologyFar East State UniversityVladivostokRussia

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