Russian Journal of Coordination Chemistry

, Volume 32, Issue 8, pp 545–551 | Cite as

Interpretation of the IR spectra of aluminum, gallium, and indium tris(acetylacetonates)

  • S. N. Slabzhennikov
  • O. B. Ryabchenko
  • L. A. Kuarton


The IR spectra of M(Acac)3 (M = Al, Ga, and In; Acac−1 is the acetylacetonate ion) and their isotope-substituted analogs were calculated by the Hartree-Fock-Roothaan method. The results obtained and available literature data were used to assign the absorption bands. A correlation was found between the force constants of the M-O bond and the stability constants of the complexes M(Acac)3.


Acac Stability Constant Force Constant Coordination Chemistry Molecular Complex 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
  2. 2.
    Schmidt, M.W., Baldzidge, K.K., Boatz, J.A., et al., J. Comput. Chem., 1993, vol. 14, p. 1347.CrossRefGoogle Scholar
  3. 3.
    Modern Theoretical Chemistry, Gerald and Segal, Eds., New York: Plenum, vol. 8, 1977.Google Scholar
  4. 4.
    Gribov, L.A., Zolotov, Yu.A., and Noskova, M.P., Zh. Strukt. Khim., 1968, vol. 9, no. 3, p. 448.Google Scholar
  5. 5.
    Flükiger, P., Lüthi, H.P., Portmann, S., and Weber, J., MOLEKEL 4.3, Manno (Switzerland): Swiss Center for Scientific Computing, 2000–2002.Google Scholar
  6. 6.
    Portmann, S. and Lüthi, H.P., MOLEKEL: An Interactive Molecular Graphics. Tool. CHIMIA, 2000, vol. 54, no. 11, p. 766.Google Scholar
  7. 7.
    Djordevic, C., Spectrochim. Acta, 1961, vol. 17, no. 7, p. 448.CrossRefGoogle Scholar
  8. 8.
    Dismukes, J.P., Jones, L.H., and Bailar, J.C., J. Phys. Chem., 1961, vol. 65, no. 5, p. 792.Google Scholar
  9. 9.
    Jablonski, Z. and Rychlowska-Himmel, I., Spectrochim. Acta, Part A, 1979, vol. 35, no. 8, p. 1297.CrossRefGoogle Scholar
  10. 10.
    Junge, H. and Musso, H., Spectrochim. Acta, Part A, 1968, vol. 24, no. 8, p. 1219.CrossRefGoogle Scholar
  11. 11.
    Tayyari, S.F., Raissi, H., and Ahmadabadi, Z., Spectrochim. Acta, Part A, vol. 58, no. 12, p. 2669.Google Scholar
  12. 12.
    Nakamoto, K., McCarthy, P.J., and Martell, A.E., J. Am. Chem. Soc., 1961, vol. 83, no. 5, p. 1066.CrossRefGoogle Scholar
  13. 13.
    Gerasimchuk, A.I., Cand. Sci. (Chem.) Dissertation, Kiev: Institute of General and Inorganic Chemistry, Ukr.SSR Academy of Sciences, 1984.Google Scholar
  14. 14.
    Thornton, D.A., Coord. Chem. Rev., 1990, vol. 104, no. 2, p. 173.CrossRefGoogle Scholar
  15. 15.
    Diaz-Acosta, I., Baker, J., Cordes, W., and Pulay, P., J. Phys. Chem. A, 2001, vol. 105, no. 1, p. 238.CrossRefGoogle Scholar
  16. 16.
    Sverdlov, L.M., Kovner, M.A., and Krainov, E.P., Kolebatel’nye spektry molekul (Vibrational Spectra of Molecules), Moscow: Nauka, 1970.Google Scholar

Copyright information

© Pleiades Publishing, Inc. 2006

Authors and Affiliations

  • S. N. Slabzhennikov
    • 1
  • O. B. Ryabchenko
    • 1
  • L. A. Kuarton
    • 1
  1. 1.Institute of Physics and Information TechnologyFar East State UniversityVladivostokRussia

Personalised recommendations