, Volume 61, Issue 1, pp 5–11 | Cite as

Gas-Phase Conversion of Uranium Mononitride in a Nitrating Atmosphere

  • S. A. KulyukhinEmail author
  • Yu. M. Nevolin
  • A. V. Gordeev


Gas-phase conversion of UN to water-soluble compounds in NOx-air, NOx-H2O (vapor)-air, or HNO3 (vapor)-air atmosphere (hereinafter, nitrating atmosphere) at temperatures from 298 to 673 K was studied. The use of the oxidizing atmosphere based on NOx gases allows the conversion to be performed at a lower temperature. The process yields both UO3 and hydrates of UO2(NO3)2. The highest conversion of UN to water-soluble compounds, ∼80%, is reached at ∼565 K. In the course of gas-phase conversion in NOx-H2O (vapor)-air and HNO3 (vapor)-air atmospheres, UN transforms into water-soluble compounds (nitrates, hydroxynitrates). The gas-phase conversion of UN in an NOx-H2O (vapor)-air atmosphere occurs less efficiently than that in an HNO3 (vapor)-air atmosphere.


uranium mononitride gas-phase conversion nitrating atmosphere 


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Copyright information

© Pleiades Publishing, Inc. 2019

Authors and Affiliations

  • S. A. Kulyukhin
    • 1
    Email author
  • Yu. M. Nevolin
    • 2
  • A. V. Gordeev
    • 1
  1. 1.Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussia
  2. 2.Department of ChemistryMoscow State UniversityMoscowRussia

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