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Radiochemistry

, Volume 60, Issue 6, pp 607–612 | Cite as

Extraction of REE(III), U(VI), and Th(IV) from Nitric Acid Solutions with Carbamoylmethylphosphine Oxides in the Presence of Dinonylnaphthalenesulfonic Acid

  • A. N. TuranovEmail author
  • V. K. Karandashev
  • A. N. Yarkevich
Article
  • 9 Downloads

Abstract

The extraction of REE(III), U(VI), and Th(IV) from nitric acid solutions with solutions of carbamoylmethylphosphine oxides (CMPOs) considerably increases in the presence of dinonylnaphthalenesulfonic acid. The stoichiometry of the extractable complexes was determined, and the influence of the aqueous phase composition, kind of organic diluent, and CMPO structure on the efficiency of the extraction of the metal ions was analyzed.

Keywords

extraction REE(III) uranium(VI) thorium(IV) carbamoylmethylphosphine oxides dinonylnaphthalenesulfonic acid synergism 

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References

  1. 1.
    Rozen, A.M. and Krupnov, B.V., Russ. Chem. Rev., 1996, vol. 65, no. 11, pp. 973–1000.CrossRefGoogle Scholar
  2. 2.
    Chmutova, M.K., Litvina, M.N., Pribylova, G.A., et al., Radiochemistry, 1999, vol. 41, no. 4, pp. 349–354.Google Scholar
  3. 3.
    Myasoedova, G.V., Ross. Khim. Zh., 2005, vol. 49, no. 2, pp. 72–75.Google Scholar
  4. 4.
    Yagodin, G.A., Kagan, S.Z., Tarasov, V.V., et al., Osnovy zhidkostnoi ekstraktsii (Principles of Solvent Extraction), Moscow: Khimiya, 1981.Google Scholar
  5. 5.
    Rao, L., Xia, Y., Rapko, B.M., and Martin, P.F., Solvent Extr. Ion Exch., 1998, vol. 16, pp. 913–929.CrossRefGoogle Scholar
  6. 6.
    Turanov, A.N., Karandashev, V.K., Kharlamov, A.V., and Bondarenko, N.A., Solvent Extr. Ion Exch., 2014, vol. 32, pp. 492–507.CrossRefGoogle Scholar
  7. 7.
    Rais, J. and Tachimori, S., J. Radioanal. Nucl. Chem. Lett., 1994, vol. 188, no. 2, pp. 157–162.CrossRefGoogle Scholar
  8. 8.
    Smirnov, I.V., Radiochemistry, 2007, vol. 49, no. 1, pp. 44–54.CrossRefGoogle Scholar
  9. 9.
    Turanov, A.N., Karandashev, V.K., Sharova, E.V., et al., Radiochemistry, 2013, vol. 55, no. 2, pp. 203–207.CrossRefGoogle Scholar
  10. 10.
    Turanov, A.N., Karandashev, V.K., and Yarkevich, A.N., Radiochemistry, 2013, vol. 55, no. 4, pp. 382–387.CrossRefGoogle Scholar
  11. 11.
    Dhami, P.S., Chitnis, R.R., Gopalakrishnan, V., et al., Sep. Sci. Technol., 2001, vol. 36, pp. 325–335.CrossRefGoogle Scholar
  12. 12.
    Lumetta, G.J., Gelis, A.V., and Vandergrift, G.F., Solvent Extr. Ion Exch., 2010, vol. 28, pp. 287–312.CrossRefGoogle Scholar
  13. 13.
    Tkac, P., Vandergrift, G.F., Lumetta, G.J., and Gelis, A.V., Ind. Eng. Chem. Res., 2012, vol. 51, pp. 10 433–10 444.CrossRefGoogle Scholar
  14. 14.
    Agafonova-Moroz, M.S., Krasnikov, L.V., Mishina, N.E., et al., Radiochemistry, 2009, vol. 51, no. 4, pp. 403–405.CrossRefGoogle Scholar
  15. 15.
    Ramadan, A., Mahmoud, M., Khalifa, S.M., and Souka, N., J. Radioanal. Nucl. Chem. Lett., 1993, vol. 176, pp. 457–470.CrossRefGoogle Scholar
  16. 16.
    Chmutova, M.K., Ivanova, L.A., Kochetkova, N.E., et al., Radiokhimiya, 1995, vol. 37, no. 5, pp. 422–426.Google Scholar
  17. 17.
    Chmutova, M.K., Litvina, M.N., Pribylova, G.A.., et al., Radiokhimiya, 1995, vol. 37, no. 5, pp. 430–435.Google Scholar
  18. 18.
    Litvina, M.N., Chmutova, M.K., Pribylova, G.A., et al., Radiochemistry, 1998, vol. 40, no. 6, pp. 573–577.Google Scholar
  19. 19.
    Turanov, A.N., Karandashev, V.K., Kharitonov, A.V., et al., Russ. J. Gen. Chem., 1999, vol. 69, no. 7, pp. 1068–1074.Google Scholar
  20. 20.
    Danesi, P.R., Chiarizia, R., and Scibona, G., J. Inorg. Nucl. Chem., 1973, vol. 35, pp. 3926–3928.CrossRefGoogle Scholar
  21. 21.
    Turanov, A.N., Karandashev, V.K., Baulin, V.E., and Tsvetkov, E.N., Zh. Neorg. Khim., 1995, vol. 40, no. 11, pp. 1926–1930.Google Scholar
  22. 22.
    Naganawa, H., Suzuki, H., Tachimori, S., et al., Phys. Chem. Chem. Phys., 2001, vol. 3, pp. 2509–2517.CrossRefGoogle Scholar
  23. 23.
    Nayak, P.K., Kumaresan, R., Venkatesan, K.A., et al., Sep. Sci. Technol., 2013, vol. 48, pp. 1409–1416.CrossRefGoogle Scholar
  24. 24.
    Hogfeldt, E., Chiarizia, R., Danesi, P.R., and Soldatov, V.S., Chem. Scr., 1981, vol. 18, pp. 13–43.Google Scholar
  25. 25.
    Out, E.O. and Westland, A.D., Solvent Extr. Ion Exch., 1991, vol. 9, pp. 875–883.CrossRefGoogle Scholar
  26. 26.
    Yatsimirskii, K.B., Kostromina, N.A., Sheka, Z.A., et al., Khimiya kompleksnykh soedinenii redkozemel’nykh elementov (Chemistry of Coordination Compounds of Rare Earth Elements), Kiev: Naukova Dumka, 1966.Google Scholar
  27. 27.
    Rozen, A.M., Nikiforov, A.S., Nikolotova, Z.I., and Kartasheva, N.A., Dokl. Akad. Nauk SSSR, 1986, vol. 286, no. 3, pp. 667–670.Google Scholar
  28. 28.
    Shadrin, A.Yu., Babain, V.A., and Kiseleva, R.N., Radiokhimiya, 1993, vol. 35, no. 1, pp. 45–50.Google Scholar
  29. 29.
    Kabachnik, M.I., Myasoedov, B.F., Mastryukova, T.A., et al., Russ. Chem. Bull., 1996, vol. 45, no. 11, pp. 2484–2490.CrossRefGoogle Scholar
  30. 30.
    Litvina, M.N., Chmutova, M.K., Myasoedov, B.F., and Kabachnik, M.I., Radiokhimiya, 1996, vol. 38, no. 6, pp. 525–530.Google Scholar
  31. 31.
    Kochetkova, N.E., Koiro, O.E., Nesterova, N.P., et al., Radiokhimiya, 1986, vol. 28, no. 3, pp. 338–345.Google Scholar
  32. 32.
    Turanov, A.N., Karandashev, V.K., and Yarkevich, A.N., Radiochemistry, 2012, vol. 54, no. 5, pp. 477–482.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Inc. 2018

Authors and Affiliations

  • A. N. Turanov
    • 1
    Email author
  • V. K. Karandashev
    • 2
    • 3
  • A. N. Yarkevich
    • 4
  1. 1.Institute of Solid State PhysicsRussian Academy of SciencesChernogolovka, Moscow oblastRussia
  2. 2.Institute of Microelectronics Technology and High-Purity MaterialsRussian Academy of SciencesMoscow oblastRussia
  3. 3.Moscow Institute of Steel and AlloysNational Research University of TechnologyMoscowRussia
  4. 4.Institute of Physiologically Active CompoundsRussian Academy of SciencesChernogolovka, Moscow oblastRussia

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