Advertisement

Radiochemistry

, Volume 60, Issue 5, pp 507–513 | Cite as

Synthesis, Structure, and Spectral Properties of Mixed Uranyl Hydroxonitrate Complexes [(CH3)4N]2[(UO2)2(NO3)4(OH)2] and (HMeIm)2[(UO2)2(NO3)4(OH)2] (MeIm = 1-Methylimidazole)

  • A. A. ShiryaevEmail author
  • A. M. Fedoseev
  • M. S. Grigor’ev
  • A. A. Averin
Article
  • 9 Downloads

Abstract

The structure and spectroscopic properties of two mixed-ligand uranyl complexes, [(CH3)4N]2· [(UO2)2(NO3)4(OH)2] and [(UO2)2(NO3)4(H2O)2]·2Im (Im = imidazole), were studied by single crystal X-ray diffraction and by vibrational and photoluminescence spectroscopy. The previously made assumption that the latter compound contains electrically neutral complexes [(UO2)2(NO3)4(H2O)2] was found to be erroneous; actually both compounds contain dimeric anions [(UO2)2(NO3)4(OH)2]2–.

Keywords

uranyl hydroxonitrates single crystal X-ray diffraction analysis vibrational spectroscopy photoluminescence spectroscopy 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Krivovichev, S.V. and Kahlenberg, V., Z. Anorg. Allg. Chem., 2005, vol. 631, pp. 2352–2357.CrossRefGoogle Scholar
  2. 2.
    Liu, D.-S., Huang, G.-S., Luo, Q.-Y., et al., Acta Crystallogr., Sect. E, 2006, vol. 62, pp. 1584–1585.CrossRefGoogle Scholar
  3. 3.
    Doran, M.B., Norquist, A.J., and O’Hare, D., Acta Crystallogr., Sect. E, 2003, vol. 59, pp. 373–375.CrossRefGoogle Scholar
  4. 4.
    Ivanova, A.G., Grigor’ev, M.S., and Fedoseev, A.M., Radiochemistry, 2018, vol. 60, no. 2, pp. 148–151.CrossRefGoogle Scholar
  5. 5.
    Perry, D.L., Ruben, H., Templeton, D.H., and Zalkin, A., Inorg. Chem., 1980, vol. 19, pp. 1067–1069.CrossRefGoogle Scholar
  6. 6.
    APEX2, Madison, Wisconsin (USA): Bruker AXS, 2007.Google Scholar
  7. 7.
    SAINT-Plus, version 7.68, Madison, Wisconsin (USA): Bruker AXS, 2007.Google Scholar
  8. 8.
    Sheldrick, G.M., SADABS, Madison, Wisconsin (USA): Bruker AXS, 2008.Google Scholar
  9. 9.
    Sheldrick, G.M., Acta Crystallogr., Sect. A, 2008, vol. 64, pp. 112–122.CrossRefGoogle Scholar
  10. 10.
    Sheldrick, G.M., Acta Crystallogr., Sect. C, 2015, vol. 71, pp. 3–8.CrossRefGoogle Scholar
  11. 11.
    Cejka, J., Uranium: Mineralogy, Geochemistry, and the Environment, vol. 38 of Reviews in Mineralogy and Geochemistry, Burns, P.C. and Finch, R., Eds., 1999, pp. 521–622.Google Scholar
  12. 12.
    Sidorenko, G.V., Dushin, R.B., Legin, E.K., and Suglobov, D.N., Radiokhimiya, 1981, vol. 23, no. 3, pp. 400–406.Google Scholar
  13. 13.
    Sidorenko, G.V., Dushin, R.B., Legin, E.K., and Suglobov, D.N., Radiokhimiya, 1981, vol. 23, no. 3, pp. 407–412.Google Scholar
  14. 14.
    Bartlett, J.R. and Cooney, R.P., J. Mol. Struct., 1989, vol. 193, pp. 295–300.CrossRefGoogle Scholar
  15. 15.
    Denning, R.G., Electronic Structure and Bonding in Actinyl Ions, vol. 79 of Complexes, Clusters and Crystal Chemistry. Structure and Bonding, Berlin: Springer, 1992.CrossRefGoogle Scholar
  16. 16.
    Bullock, J.I., J. Chem. Soc. A, 1969, pp. 781–784.Google Scholar
  17. 17.
    Denning, R.G., Snellgrove, T.R., and Woodwark, D.R., Mol. Phys., 1976, vol. 32, pp. 419–442.CrossRefGoogle Scholar
  18. 18.
    Brittain, H.G. and Perry, D.L., J. Phys. Chem., 1980, vol. 84, pp. 2630–2634.CrossRefGoogle Scholar
  19. 19.
    Hamalainen, R., Turpeinen, U., and Mutikainen, I., Acta Crystallogr., Sect. C, 1996, vol. 52, pp. 16–17.CrossRefGoogle Scholar
  20. 20.
    Hazra, S., Sasmal, S., Nayak, M., et al., CrystEng-Comm, 2010, vol. 12, p.470.CrossRefGoogle Scholar
  21. 21.
    Bhattacharya, S., Jana, A., and Mohanta, S., CrystEng-Comm, 2013, vol. 15, pp. 10374–10382.CrossRefGoogle Scholar
  22. 22.
    Fischer, A. and Palladino, G., Acta Crystallogr., Sect. E, 2005, vol. 61, pp. 1542–1544.CrossRefGoogle Scholar
  23. 23.
    Spencer, E.C., Kalyanasundari, B., Mariyatra, M.B., et al., Inorg. Chim. Acta, 2006, vol. 359, pp. 35–43.CrossRefGoogle Scholar
  24. 24.
    Cocalia, V., Smiglak, M., Kelley, S.P., et al., Eur. J. Inorg. Chem., 2010, vol. 2010, no. 18, pp. 2760–2767.CrossRefGoogle Scholar
  25. 25.
    Qu, F., Zhu, Q.-Q., and Liu, C.-L., Cryst. Growth Des., 2014, vol. 14, pp. 6421–6432.CrossRefGoogle Scholar
  26. 26.
    Voissat, B., Dung, N.-H., and Soye, C., Acta Crystallogr., Sect. C, 1983, vol. 39, pp. 573–576.CrossRefGoogle Scholar
  27. 27.
    Bhattacharya, S., Jana, A., Fleck, M., and Mohanta, S., Inorg. Chim. Acta, 2013, vol. 405, pp. 196–202.CrossRefGoogle Scholar
  28. 28.
    Bhattacharya, S., Mondal, S., Sasmal, S., et al., Cryst-EngComm, 2011, vol. 13, pp. 1029–1036.CrossRefGoogle Scholar
  29. 29.
    Deshayes, L., Keller, N., Lance, M., et al., Acta Crystallogr., Sect. C, 1993, vol. 49, pp. 16–19.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Inc. 2018

Authors and Affiliations

  • A. A. Shiryaev
    • 1
    • 2
    Email author
  • A. M. Fedoseev
    • 1
  • M. S. Grigor’ev
    • 1
  • A. A. Averin
    • 1
  1. 1.Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussia
  2. 2.Institute of Geology of Ore Deposits, Petrography, Mineralogy, and GeochemistryRussian Academy of SciencesMoscowRussia

Personalised recommendations