Physics of the Solid State

, Volume 61, Issue 11, pp 2233–2240 | Cite as

Synthesis of Poly(2-(cyclopent-2-en-1-yl)aniline) and Investigation of Its Electrophysical and Physicochemical Properties

  • Yu. N. Biglova
  • R. B. SalikhovEmail author
  • I. N. Safargalin
  • T. R. Salikhov
  • A. G. Mustafin


A new electron donating polymer poly(2-(cyclopent-2-enyl)aniline) is synthesized, and synthesis parameters such as monomer-to-oxidant molar ratio and reaction duration are optimized. The separability of the target product (i.e., functionalized polyaniline) and its solubility in a series of conventional organic solvents with different polarity are estimated. The synthesized high-molecular weight product is studied by thermogravimetry analysis, the temperature dependence of its electrical conductivity is investigated, and the charge carrier mobilities are calculated.


polyaniline thin films electrical conductivity morphology thermogravimetry 



The work was supported within a state assignment (topic no. AAAA-A19-119020890014-7).


The authors declare that they have no conflicts of interest.


  1. 1.
    J. Stejskal and R. G. Gilbert, Pure Appl. Chem. 74, 857 (2002).CrossRefGoogle Scholar
  2. 2.
    T. Blythe and D. Bloor, Electrical Properties of Polymers (Cambridge Univ. Press, Cambridge, 2005).Google Scholar
  3. 3.
    V. A. Moshnikov and E. I. Terukov, The Basics of Hydrogen Energy (LETI, St. Petersburg, 2011), p. 288 [in Russian].Google Scholar
  4. 4.
    I. Yu. Pinus, A. B. Yaroslavtsev, E. N. Nasybullin, V. G. Sergeev, and V. A. Kabanov, Russ. J. Inorg. Chem. 51, 964 (2006).CrossRefGoogle Scholar
  5. 5.
    D. C. Trivedi, in Handbook of Organic Conductive Molecules and Polymers, Ed. by H. S. Nalwa (Wiley, Chichester, 1997), Vol. 2.Google Scholar
  6. 6.
    T. J. Rivers, T. W. Hudson, and C. E. Schmidt, Adv. Func. Mater. 12, 33 (2002).CrossRefGoogle Scholar
  7. 7.
    T. F. Otero, J. G. Martinez, and J. Arias-Pardilla, Electrochim. Acta 84, 112 (2012).CrossRefGoogle Scholar
  8. 8.
    B. Wessling, Synth. Met. 3, 143 (1998).CrossRefGoogle Scholar
  9. 9.
    S. Bhadra, D. Khastgir, N. K. Singha, and J. H. Lee, Prog. Polym. Sci. 34, 783 (2009).CrossRefGoogle Scholar
  10. 10.
    E. M. Genieś, A. Boyle, M. Lapkowski, and C. Tsintavis, Synth. Met. 36, 139 (1990).CrossRefGoogle Scholar
  11. 11.
    Yu. N. Biglova, R. B. Salikhov, I. B. Abdrakhmanov, T. P. Salikhov, I. N. Safargalin, and A. G. Mustafin, Phys. Solid State 59, 1253 (2017).ADSCrossRefGoogle Scholar
  12. 12.
    D. D. Borole, U. R. Kapadi, P. P. Mahulikar, and D. G. Hundiwale, Mater. Lett. 58, 3816 (2004).CrossRefGoogle Scholar
  13. 13.
    D. D. Borole, U. R. Kapadi, P. P. Mahulikar, and D. G. Hundiwale, Mater. Lett. 60, 2447 (2006).CrossRefGoogle Scholar
  14. 14.
    I. L. Knunyants, Chemical Encyclopedical Dictionary (Sov. Entsiklopediya, Moscow, 1983) [in Russian].Google Scholar
  15. 15.
    L. Tittse and G. Aikher, Reactions and Syntheses in the Organic Chemistry Laboratory (Univ. Sci., Mill Valley, 1989; Mir, Moscow, 1999).Google Scholar
  16. 16.
    I. B. Abdrakhmanov, A. G. Mustafin, and V. M. Sharafutdinov, Kleisen Rearrangement in a Series of Aromatic Amines (Gilem, Ufa, 2014) [in Russian].Google Scholar
  17. 17.
    T. Higuchi and K. A. Connors, Adv. Anal. Chem. Instrum. 4, 117 (1965).Google Scholar
  18. 18.
    L. Y. O. Yang, C. Z. Chang, S. H. Liu, S. G. Wu, and S. L. Yau, J. Am. Chem. Soc. 129, 8067 (2007).Google Scholar
  19. 19.
    R. B. Salikhov, A. A. Bunakov, and A. N. Lachinov, Phys. Solid State 49, 185 (2007).ADSCrossRefGoogle Scholar
  20. 20.
    R. B. Salikhov, A. N. Lachinov, and R. G. Rakhmeyev, Mol. Cryst. Liq. Cryst. 467, 85 (2007).CrossRefGoogle Scholar
  21. 21.
    Y.-C. Li, Y.-J. Lin, H.-J. Yeh, T.-C. Wen, L.-M. Huang, Y.-K. Chen, and Y.-H. Wang, Appl. Phys. Lett. 92, 093508 (2008).ADSCrossRefGoogle Scholar
  22. 22.
    H. D. Tran, J. M. D’Arcy, Y. Wang, P. J. Beltramo, V. A. Strong, and R. B. Kaner, J. Mater. Chem. 21, 3534 (2011).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • Yu. N. Biglova
    • 1
    • 2
  • R. B. Salikhov
    • 2
    Email author
  • I. N. Safargalin
    • 2
  • T. R. Salikhov
    • 2
  • A. G. Mustafin
    • 1
    • 2
  1. 1.Ufa Institute of Chemistry, Ufa Federal Research Center, Russian Academy of SciencesUfaRussia
  2. 2.Bashkir State UniversityUfaRussia

Personalised recommendations