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Physics of the Solid State

, Volume 59, Issue 10, pp 2030–2035 | Cite as

Electronic structure of nitrogen-containing carbon nanotubes irradiated with argon ions: XPS and XANES studies

  • S. N. Nesov
  • P. M. Korusenko
  • V. V. Bolotov
  • S. N. Povoroznyuk
  • D. A. Smirnov
Low-Dimensional Systems
  • 42 Downloads

Abstract

Using the methods of X-ray photoelectron (XPS) and X-ray absorption near edge structure (XANES) spectroscopies with synchrotron radiation, data on changes in the electronic structure and chemical composition of nitrogen-containing multiwalled carbon nanotubes (N-MWCNTs) upon their exposure to the radiation of argon ions with an energy of 5 keV are obtained. It is found that the exposure leads to an increase in the degree of defectiveness of the N-MWCNTs structure and to the carbon oxidation with formation of various oxygen-containing groups (C–OH, C=O/COOH, C–O–C/O–C–O, and CO3). The presence of carbon–oxygen bonds on the surface of carbon nanotubes is associated with the formation of radiation defects. It is shown that an increase in the fraction of nitrogen atoms present in the substituting configuration in the N-MWCNTs wall structure due to the irradiation does not give rise to an increase in the density of the occupied states near the Fermi level against the background of an increase in the degree of structure defectiveness, carbon oxidation, and a decrease in the total nitrogen concentration. The obtained results show that the irradiation of N-MWCNTs with argon ions allows one to successfully functionalize their surface.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • S. N. Nesov
    • 1
  • P. M. Korusenko
    • 1
  • V. V. Bolotov
    • 1
  • S. N. Povoroznyuk
    • 1
    • 2
  • D. A. Smirnov
    • 3
    • 4
  1. 1.Omsk Scientific Center, Siberian BranchRussian Academy of SciencesOmskRussia
  2. 2.Omsk State Technical UniversityOmskRussia
  3. 3.St. Petersburg State UniversitySt. PetersburgRussia
  4. 4.Institute of Solid State PhysicsDresden University of TechnologyDresdenGermany

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