Physics of the Solid State

, Volume 59, Issue 2, pp 368–377 | Cite as

Electronic structure of nickel porphyrin NiP: Study by X-ray photoelectron and absorption spectroscopy

  • G. I. Svirskiy
  • N. N. Sergeeva
  • S. A. Krasnikov
  • N. A. Vinogradov
  • Yu. N. Sergeeva
  • A. A. Cafolla
  • A. B. Preobrajenski
  • A. S. Vinogradov
Low-Dimensional Systems
  • 55 Downloads

Abstract

Energy distributions and properties of the occupied and empty electronic states for a planar complex of nickel porphyrin NiP are studied by X-ray photoemission and absorption spectroscopy techniques. As a result of the analysis of the experimental spectra of valence photoemission, the nature and energy positions of the highest occupied electronic states were determined: the highest occupied state is formed mostly by atomic states of the porphine ligand; the following two states are associated with 3d states of the nickel atom. It was found that the lowest empty state is specific and is described by the σ-type b1g MO formed by empty \(Ni3{d_{{x^2} - {y^2}}}\)-states and occupied 2p-states of lone electron pairs of nitrogen atoms. This specific nature of the lowest empty state is a consequence of the donor–acceptor chemical bond in NiP.

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Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • G. I. Svirskiy
    • 1
  • N. N. Sergeeva
    • 2
  • S. A. Krasnikov
    • 1
    • 3
  • N. A. Vinogradov
    • 1
    • 4
  • Yu. N. Sergeeva
    • 5
  • A. A. Cafolla
    • 3
  • A. B. Preobrajenski
    • 1
    • 4
  • A. S. Vinogradov
    • 1
  1. 1.Saint Petersburg State UniversitySt. PetersburgRussia
  2. 2.School of ChemistryUniversity of LeedsLeedsUK
  3. 3.School of Physical SciencesDublin City UniversityGlasnevin, Dublin 9Ireland
  4. 4.MAX IV LaboratoryUniversity of LundLundSweden
  5. 5.Commissariat à l’Énergie Atomique et aux Énergies AlternativesInstitut Nanosciences et CryogénieGrenoble Cedex 9France

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