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Crystallography Reports

, Volume 63, Issue 7, pp 1124–1128 | Cite as

Synthesis and Structural Characterization of a Cobalt Coordination Polymer with Bis(4-(1H-imidazol-1-yl)phenyl)methanone and 4-Nitrophthalate

  • G.-F. WangEmail author
  • S.-W. Sun
STRUCTURE OF ORGANIC COMPOUNDS

Abstract

A cobalt coordination polymer having the formula of [Co(npa)(L1)(H2O)2]n (1), where L1 is a bis(4-(1H-imidazol-1-yl)phenyl)methanone and H2npa is a 4-nitrophthalic acid, has been synthesized and structurally characterized. Single crystal X-ray diffraction analysis shows that the Co1 has a distorted octahedral geometry with four O atoms from two npa2– ligands and two N atoms from two L1 ligands, while the Co2 has the same coodination geometry with four O atoms from coordinating water molecules and two N atoms from two L1 ligands. Each L1 acts as a bridging ligand to link neighboring Co ions to form a 1D chain.

Notes

ACKNOWLEDGMENTS

We are grateful for financial support from the Young Teacher Starting-up Research of Yuncheng University (no. YQ-2015007 to GFW), Undergraduate Training Program for Innovation and Entrepreneurship of Yuncheng University (DC2017170).

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Copyright information

© Pleiades Publishing, Inc. 2018

Authors and Affiliations

  1. 1.Department of Applied Chemistry, Yuncheng UniversityYunchengChina

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