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Crystallography Reports

, Volume 63, Issue 7, pp 1133–1137 | Cite as

Molecular and Crystalline Structure of the Ruthenium(II) Complex [{trans-(dppe)2(Cl) Ru–C≡C–H} · 0.5CDCl3]: An Additional Determination

  • C. A. Escobar
  • F. Madrid-Moliné
  • M. Fuentealba
  • J. C. Santos
  • P. Jara-Ulloa
  • A. TrujilloEmail author
STRUCTURE OF ORGANIC COMPOUNDS

Abstract

The synthesis and X-ray diffraction study of the ruthenium(II) complex, [{trans-(dppe)2(Cl) Ru–C≡C–H} · 0.5CDCl3] (trans-Ru · 0.5CDCl3), are presented. The molecule of trans-Ru · 0.5CDCl3 crystallizes in the triclinic sp. gr. \(P\bar {1}\) with two chemically equivalent but crystallographic independent molecules. The intramolecular C–H···Cl–C hydrogen bonds build with the deuterated chloroform. In addition, the intermolecular C–H···Cl–Ru hydrogen bonds have been also found.

Notes

ACKNOWLEDGMENTS

The authors gratefully acknowledge the financial support from the UNAB (grant no. DI-5-17/RG). In addition, the authors gratefully acknowledge the use of the services and facilities of the Laboratorio de Análisis de Sólidos (L.A.S-UNAB) at the Universidad Andrés Bello. The authors thank Poldie Oyarzun for technical assistance using the D8 Smart Apex II Bruker AXS diffractometer.

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Copyright information

© Pleiades Publishing, Inc. 2018

Authors and Affiliations

  • C. A. Escobar
    • 1
  • F. Madrid-Moliné
    • 1
  • M. Fuentealba
    • 2
  • J. C. Santos
    • 1
  • P. Jara-Ulloa
    • 1
  • A. Trujillo
    • 1
    Email author
  1. 1.Facultad de Ciencias Exactas, Departamento de Ciencias Químicas, Universidad Andres BelloSantiagoChile
  2. 2.Facultad de Ciencias, Instituto de Química, Pontificia Universidad Católica de Valparaíso, CuraumaValparaísoChile

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