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Crystallography Reports

, Volume 63, Issue 7, pp 1195–1199 | Cite as

New Cluster Concept of Crystal Formation

  • A. M. AskhabovEmail author
CRYSTAL GROWTH
  • 31 Downloads

Abstract

Some new models of crystal nucleation and growth, which make it possible to form fundamentals of nonclassical cluster paradigm of crystal formation, have been proposed within the theory of cluster self-organization of material on the nanoscale. According to these models, crystal nucleation occurs according to the two-step mechanism through the formation of peculiar nanoclusters (“hidden”-phase clusters or quatarons) in the crystal-forming medium. These clusters are also considered to be the main building units during crystal growth.

Notes

ACKNOWLEDGMENTS

The studies aimed at developing the cluster concept of crystal formation were supported by the Russian Foundation for Basic Research and the Program for Fundamental Research of the Ural Branch of the Russian Academy of Sciences.

REFERENCES

  1. 1.
    E. S. Fedorov, Priroda, December, 1471 (1915).Google Scholar
  2. 2.
    D. Balarev, Stroezh na Realnokristalnite Sistemy (Nauka i Izkustvo, Sofiya, 1964).Google Scholar
  3. 3.
    N. P. Yushkin, Theory of Microassembly Crystal Growth in Natural Heterogeneous Solutions, Ser. Scientific Reports (Komi Branch AN Soviet Union, Syktyvkar, 1971) [in Russian].Google Scholar
  4. 4.
    P. P. Fedorov, V. K. Ivanov, and V. V. Osiko, Dokl. Phys. 60 (11), 483 (2015).ADSCrossRefGoogle Scholar
  5. 5.
    V. K. Ivanov, P. P. Fedorov, A. E. Baranchikov, and V. V. Osiko, Usp. Khim., No. 1, 1204 (2015).Google Scholar
  6. 6.
    R. O. Grizdeil, Theory and Practice of Crystal Growth (Nauka, Moscow, 1968) [in Russian], p. 176.Google Scholar
  7. 7.
    L. N. Rashkovich, Physics of Crystallization (Nauchnyi Mir, Moscow, 2015) [in Russian].Google Scholar
  8. 8.
    G. D. Ilyushin and L. N. Dem’yanets, Physics of Crystallization (Nauchnyi Mir, Moscow, 2002) [in Russian], p. 82.Google Scholar
  9. 9.
    A. M. Askhabov and M. A. Ryazanov, Dokl. Akad. Nauk 362 (5), 630 (1998).Google Scholar
  10. 10.
    J. J. de Yoreo and P. G. Vekilov, Biomineralization, Ed. by P. M. Dove (Mineralogical Society of America, Washington, 2003), Vol. 54, p. 57.Google Scholar
  11. 11.
    P. G. Vekilov, Cryst. Growth Des. 4, 671 (2004).CrossRefGoogle Scholar
  12. 12.
    D. Erdemir, A. Y. Lee, and A. S. Myerson, Chem. Res. 42, 621 (2009).CrossRefGoogle Scholar
  13. 13.
    R. P. Sear, Int. Mater. Rev. 57, 328 (2012).CrossRefGoogle Scholar
  14. 14.
    J. De Yoreo, Nature Mater. 12, 284 (2013).ADSCrossRefGoogle Scholar
  15. 15.
    E. Sanz, C. Vega, J. R. Espinosa, et al., J. Am. Chem. Soc. 135 (40), 15008 (2013).CrossRefGoogle Scholar
  16. 16.
    J. J. De Yoreo, P. U. Gilbert, N. A. Sommerdijk, et al., Science 349, 6760 (2015).CrossRefGoogle Scholar
  17. 17.
    N. Duane, S. Sen, M. Bosman, et al., Nature Chem. 9 (1), 77 (2017).ADSGoogle Scholar
  18. 18.
    A. M. Askhabov, Zap. Vseross. Mineral. O-va 133 (4), 108 (2004).Google Scholar
  19. 19.
    H. Reiss, H. L. Frish, E. Hefland, and J. L. Lebowitz, J. Chem. Phys. 32 (1), 119 (1960).ADSMathSciNetCrossRefGoogle Scholar
  20. 20.
    A. M. Askhabov, Phys. Solid State 47 (6), 1186 (2005).ADSCrossRefGoogle Scholar
  21. 21.
    T. T. Rusli, G. L. Schrader, and M. A. Larson, J. Cryst. Growth 97, 345 (1989).ADSCrossRefGoogle Scholar
  22. 22.
    D. Gebauer, M. Kellermeier, J. D. Gale, et al., Chem. Soc. Rev., No. 43, 2348 (2014).Google Scholar
  23. 23.
    J. Voigstberger, S. Zeller, J. Becht, et al., Nature Commun., No. 5, 5765 (2014).Google Scholar
  24. 24.
    A. M. Askhabov, Ural Mineralogical Collected Works (Institute of Mineralogy, Ural Branch, RAS, Miass, 1999) [in Russian], p. 22.Google Scholar
  25. 25.
    R. V. Galiulin, Crystallographic Geometry (Nauka, Moscow, 1984) [in Russian].zbMATHGoogle Scholar
  26. 26.
    P. Engel, Geometric Crystallography: An Axiomatic Introduction to Crystallography (Reidel, Dordrecht, 1986), p. 266.CrossRefzbMATHGoogle Scholar
  27. 27.
    P. G. Vekilov, Nanoscale 2, 2346 (2010).ADSCrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Inc. 2018

Authors and Affiliations

  1. 1.Institute of Geology of the Komi Science Center, Ural Branch, Russian Academy of SciencesSyktyvkarRussia

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