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Crystallography Reports

, Volume 61, Issue 6, pp 945–953 | Cite as

Preparation and analysis of multilayer composites based on polyelectrolyte complexes

  • V. A. Petrova
  • A. S. Orekhov
  • D. D. Chernyakov
  • Yu. G. Baklagina
  • D. P. Romanov
  • S. V. Kononova
  • A. V. Volod’ko
  • I. M. Ermak
  • V. V. KlechkovskayaEmail author
  • Yu. A. Skorik
Structure of Organic Compounds

Abstract

A method for preparing multilayer film composites based on chitosan has been developed by the example of polymer pairs: chitosan–hyaluronic acid, chitosan–alginic acid, and chitosan–carrageenan. The structure of the composite films is characterized by X-ray diffractometry and scanning electron microscopy. It is shown that the deposition of a solution of hyaluronic acid, alginic acid, or carrageenan on a chitosan gel film leads to the formation of a polyelectrolyte complex layer at the interface, which is accompanied by the ordering of chitosan chains in the surface region; the microstructure of this layer depends on the nature of contacting polymer pairs.

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References

  1. 1.
    C. Clasen, T. Wilhelms, and W. M. Kulicke, Biomacromolecules 7, 3210 (2006).CrossRefGoogle Scholar
  2. 2.
    H. H. Schwarz, J. Lukas, and K. Richau, J. Membr. Sci. 218, 1 (2003).CrossRefGoogle Scholar
  3. 3.
    S. Knop, H. Thielking, and W. M. Kulicke, J. Appl. Polym. Sci. 77, 3169 (2000).CrossRefGoogle Scholar
  4. 4.
    Yu. P. Kuznetsov, E. V. Kruchinina, L. A. Nud’ga, et al., Zh. Prikl. Khim. 76 (11), 1857 (2003).Google Scholar
  5. 5.
    L. S. Gal’braikh, Soros. Obrazovat. Zh. 7 (1), 51 (2001).Google Scholar
  6. 6.
    S. Salmon and S. M. Hudson, J. Mol. Struct. Rev. Macromol. Chem. Phys. C 37 (2), 199 (1997).Google Scholar
  7. 7.
    Yu. G. Baklagina, S. V. Kononova, V. A. Petrova, et al., Crystallogr. Rep. 58 (2), 287 (2013).ADSCrossRefGoogle Scholar
  8. 8.
    I. M. Yermak and Y. S. Khotimchenko, Chemical Properties, Biological Activities and Applications of Carrageenan from Red Algae, Ed. by M. Fingerman and R. Nagabhushanam (UK Plymouth Science, London, 2003), p. 207.Google Scholar
  9. 9.
    Ch. R. Cantor and P. R. Shimmel, Biophysical Chemistry (Freeman, San Francisco, 1984), Vol. 1.Google Scholar
  10. 10.
    A. F. Bochkov, V. A. Afanas’ev, and G. A. Zaikov, Carbohydrates (Nauka, Moscow, 1980) [in Russian].Google Scholar
  11. 11.
    W. Steplewski, D. Wawro, A. Niekraszwicz, and D. Ciechanska, Fibres Text. East. Eur. 14 (4), 25 (2006).Google Scholar
  12. 12.
    A. O. Barabanova, A. O. Shashkov, V. P. Glazunov, et al., J. Appl. Phsycol. 20 (6), 1013 (2008).CrossRefGoogle Scholar
  13. 13.
    I. M. Yermak, Y. H. Kim, et al., J. Appl. Phycol. 11, 41 (1999).CrossRefGoogle Scholar
  14. 14.
    L. A. Nud’ga, E. A. Plisko, and G. A. Petropavlovskii, USSR Inventor’s Certificate no. 757540, Byull. Izobret., 1980, no. 31, p. 286.Google Scholar
  15. 15.
    E. A. Plisko and L. A. Nud’ga, Vysokomol. Soedin. B 9 (11), 825 (1967).Google Scholar
  16. 16.
    A. L. Volynskii and N. F. Bakeev, Structural Self-Organization of Amorphous Polymers (Fizmatlit, Moscow, 2005) [in Russian].Google Scholar
  17. 17.
    K. Okuyama, K. Noguchi, R. Miyazawa, et al., Macromolecules 30 (19), 5849 (1997).ADSCrossRefGoogle Scholar
  18. 18.
    K. Okuyama, K. Noguchi, Y. Hanafusa, et al., Int. J. Biol. Macromol. 26, 285 (1999).CrossRefGoogle Scholar
  19. 19.
    K. Ogawa, S. Hirano, T. Miyanishi, et al., Macromolecules 17, 973 (1984).ADSCrossRefGoogle Scholar
  20. 20.
    J. Kawada, Y. Abe, T. Yui, et al., J. Carbohydr. Chem. 18 (5), 559 (1999).CrossRefGoogle Scholar
  21. 21.
    T. Yui, K. Imada, K. Okuyama, et al., Macromolecules 27, 7601 (1994).ADSCrossRefGoogle Scholar
  22. 22.
    K. Mazeau, W. Winter, and H. Chanzy, Macromolecules 27, 606 (1994).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Inc. 2016

Authors and Affiliations

  • V. A. Petrova
    • 1
  • A. S. Orekhov
    • 2
    • 3
  • D. D. Chernyakov
    • 4
  • Yu. G. Baklagina
    • 1
  • D. P. Romanov
    • 5
  • S. V. Kononova
    • 1
  • A. V. Volod’ko
    • 6
  • I. M. Ermak
    • 6
  • V. V. Klechkovskaya
    • 2
    Email author
  • Yu. A. Skorik
    • 1
  1. 1.Institute of Macromolecular CompoundsRussian Academy of SciencesSt. PetersburgRussia
  2. 2.Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics”Russian Academy of SciencesMoscowRussia
  3. 3.National Research Centre “Kurchatov Institute”MoscowRussia
  4. 4.St. Petersburg State Chemical Pharmaceutical AcademySt. PetersburgRussia
  5. 5.Grebenshchikov Institute of Silicate ChemistryRussian Academy of SciencesSt. PetersburgRussia
  6. 6.Elyakov Pacific Institute of Bioorganic Chemistry, Far-Eastern BranchRussian Academy of SciencesVladivostokRussia

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