Journal of Analytical Chemistry

, Volume 74, Issue 3, pp 255–261 | Cite as

On Features of the FeLα1,2 Line Used in X-ray Fluorescence Analysis for the Evaluation of the Oxidation State of Iron

  • T. G. KuzminaEmail author
  • M. A. Troneva
  • T. V. Romashova


Some specific features of the valence FeLα1,2 line are investigated: a correlation between the line intensity and the oxidation state of iron is shown; the dependence of the intensity of the FeLα1,2 line on the presence of other elements in the sample is found.


X-ray fluorescence analysis determination of the oxidation state of iron 



  1. 1.
    Filippov, M.P., Kupriyanova, T.A., and Lyamina, O.I., J. Anal. Chem., 2001, vol. 56, no. 8, p. 729.CrossRefGoogle Scholar
  2. 2.
    Chubarov, V.M. and Finkel’shtein, A.L., J. Anal. Chem., 2010, vol. 65, no. 6, p. 620.Google Scholar
  3. 3.
    Chubarov, V.M., Finkel’shtein, A.L., Suvorova, L.F., and Kostrovitskii, S.I., Zap. Ross. Mineral. O-va, 2012, vol. 141, no. 2, p. 83.Google Scholar
  4. 4.
    Albee, A.L. and Chodos, A.A., Am. Mineral., 1970, vol. 55, nos. 3–4, p. 491.Google Scholar
  5. 5.
    Fischer, D.W., J. Appl. Phys., 1965, vol. 36, no. 6, p. 2048.CrossRefGoogle Scholar
  6. 6.
    O’Nions, R.K. and Smith, D.G., Am. Mineral., 1971, vol. 56, p. 1452.Google Scholar
  7. 7.
    Verkhovodov, P.A., Rentgenospektral’nyi analiz. Voprosy teorii i sposoby unifikatsii (X-Ray Analysis: The Theory and Methods of Unification), Kiev: Naukova Dumka, 1984.Google Scholar
  8. 8.
    Pavlinskii, G.V., Osnovy fiziki rentgenovskogo izlucheniya (Fundamentals of X-Ray Physics), Moscow: FIZMATLIT, 2007.Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • T. G. Kuzmina
    • 1
    Email author
  • M. A. Troneva
    • 1
  • T. V. Romashova
    • 1
  1. 1.Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of SciencesMoscowRussia

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