Journal of Analytical Chemistry

, Volume 70, Issue 13, pp 1553–1560 | Cite as

Determination of transformation products of 1,1-dimethylhydrazine by gas chromatography–tandem mass spectrometry

  • N. V. Ul’yanovskii
  • D. S. Kosyakov
  • S. A. Pokryshkin
  • K. G. Bogolitsyn
Article

Abstract

A method is proposed for the highly sensitive simultaneous determination of eight major products of oxidative transformations of 1,1-dimethylhydrazine, widely used as a rocket fuel (formaldehyde dimethylhydrazone, acetaldehyde dimethylhydrazone, 2-furaldehyde dimethylhydrazone, 1,1,4,4-tetramethyl-2-tetrazene, N,N-dimethylformamide, N-nitrosodimethylamine, 1-methyl-1H-1,2,4-triazole and 1-formyl-2,2dimethylhydrazine) by gas chromatography–tandem mass spectrometry. The detection parameters in the MRM mode are optimized. The conditions for the efficient separation of analytes on an HP-INNOWAX polar stationary phase are chosen. The detection limits achieved are in the range 0.3–2.3 ng/mL, which is 1?2 orders of magnitude lower than those for the GC/MS method. The developed approaches are tested in the analysis of real samples, surface water of peaty swamp with high contents of organic substance taken at the place of impact of the first rocket stage. It is found that N,N-dimethylformamide and 1-methyl-1H-1,2,4-triazole are predominant among the studied transformation products in natural waters. The results obtained are of great importance for the assessment of the environmental impacts of space rocket activities.

Keywords

GC/MS-MS rocket fuel 1,1-dimethylhydrazine hydrazones N-nitrosodimethylamine 1,1,4,4-tetramethyl-2-tetrazene N,N-dimethylformamide 1-methyl-1H-1,2,4-triazole 1-formyl-2,2-dimethylhydrazine transformation products 

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References

  1. 1.
    Mitch, W.A. and Sedlak, D.L., Environ. Sci. Technol., 2002, vol. 36, no. 4, p. 588.CrossRefGoogle Scholar
  2. 2.
    Kenessov, B., Alimzhanova, M., Sailaukhanuly, Y., Baimatova, N., Abilev, M., Batyrbekova, S., Carlsen, L., Tulegenov, A., and Nauryzbayev, M., Sci. Total Environ., 2012, vols. 427–428, p. 78.CrossRefGoogle Scholar
  3. 3.
    Smirnov, R.S., Rodin, I.A., Smolenkov, A.D., and Shpigun, O.A., J. Anal. Chem., 2010, vol. 65, no. 12, p. 1266.CrossRefGoogle Scholar
  4. 4.
    Ul’yanovskii, N.V., Pokryshkin, S.A., Kosyakov, D.S., Kozhevnikov, A.Yu., Ivakhnov, A.D., and Bogolitsyn, K.G., Khim. Rastit. Syr’ya, 2012, no. 3, p. 181.Google Scholar
  5. 5.
    Kenessov, B., Koziel, J.A., Grotenhuis, T., and Carlsen, L., Anal. Chim. Acta, 2010, vol. 674, no. 1, p. 32.CrossRefGoogle Scholar
  6. 6.
    Smolenkov, A.D., Rodin, I.A., Shpak, A.V., and Shpigun, O.A., Lnt. J. Environ. Anal. Chem., 2007, vol. 87, no. 5, p. 351.CrossRefGoogle Scholar
  7. 7.
    Castanedo, G.M., Seng, P.S., Blaquiere, N., Trapp, S., and Staben, S.T., Org. Chem., 2011, vol. 76, no. 4, p. 1177.CrossRefGoogle Scholar
  8. 8.
    Selin, N.E., Environmental Guidelines and Regulations for Nitramines: A Policy Summary, Massachusetts Inst. Technol., Cambridge, 2011.Google Scholar
  9. 9.
    Dai, N. and Mitch, W.A., Environ. Sci. Technol., 2013, vol. 47, no. 8, p. 3648.CrossRefGoogle Scholar
  10. 10.
    Kenessov, B., Sailaukhanuly, Y., Koziel, J.A., Carlsen, L., and Nauryzbayev, M., Chromatographia, 2011, vol. 73, nos. 1–2, p. 123.CrossRefGoogle Scholar
  11. 11.
    Kenessov, B., Batyrbekova, S., Nauryzbayev, M., Bekbassov, T., Alimzhanova, M., and Carlsen, L., Chromatographia, 2008, vol. 67, nos. 5–6, p. 421.CrossRefGoogle Scholar
  12. 12.
    Charrois, J.W.A., Arend, M.W., Froese, K.L., and Hrudey, S.E., Environ. Sci. Technol., 2004, vol. 38, no. 18, p. 4835.CrossRefGoogle Scholar
  13. 13.
    Wang, W., Hu, J., Yu, J., and Yang, M., J. Environ. Sci., 2010, vol. 22, no. 10, p. 1508.CrossRefGoogle Scholar
  14. 14.
    Topuz, E., Aydin, E., and Pehlivanoglu-Mantas, E., Water, Air, Soil Pollut., 2012, vol. 223, no. 9, p. 5793.CrossRefGoogle Scholar
  15. 15.
    McNeill, K.S. and Cancilla, D.A., Bull. Environ. Contam. Toxicol., 2009, vol. 82, no. 3, p. 265.CrossRefGoogle Scholar
  16. 16.
    Schermerhorn, P.G., Golden, P.E., Krynitsky, A.J., and Leimkuehler, W.M., J. AOAC Int., 2005, vol. 88, no. 5, p. 1491.Google Scholar
  17. 17.
    Kosyakov, D.S., Ul’yanovskii, N.V., Bogolitsyn, K.G., and Shpigun, O.A. Int. J. Environ. Anal. Chem., 2014, vol. 94, no. 12, p. 1254. doi 10.1080/ 03067319.2014.940342CrossRefGoogle Scholar
  18. 18.
    Munch, J.W. and Bassett, M.V., Determination of Nitrosamines in Drinking Water by Solid Phase Extraction and Capillary Column Gas Chromatography with Large Volume Injection and Chemical Ionization Tandem Mass Spectrometry (MS/MS), Method 521, U.S. Environ. Protect. Agency, Ohio, 2004.Google Scholar
  19. 19.
    Class, J.B., Aston, J.G., and Oakwood, T.S., J. Am. Chem. Soc., 1953, vol. 75, no. 12, p. 2937.CrossRefGoogle Scholar
  20. 20.
    Beltrami, R.T. and Bissell, E.R., J. Am. Chem. Soc., 1956, vol. 78, no. 11, p. 2467.CrossRefGoogle Scholar
  21. 21.
    Korenman, Ya.I., Chibisova, T.V., Sukhanov, P.T., and Zybenko, M.V., Analitika Kontrol’, 2013, vol. 17, no. 4, p. 465.Google Scholar
  22. 22.
    Gulyaev, I.V., Chepelyanskii, D.A., Revel’skii, I.A., and Revel’skii, A.I., Mass-Spektrometriya, 2012, vol. 9, no. 2, p. 117.Google Scholar
  23. 23.
    Buryak, A.K. and Serdyuk, T.M., Usp. Khim., 2013, vol. 82, no. 4, p. 369.CrossRefGoogle Scholar
  24. 24.
    Kalia, J. and Raines, R.T., Angew. Chem., Int. Ed. Engl., 2008, vol. 47, no. 39, p. 7523.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • N. V. Ul’yanovskii
    • 1
  • D. S. Kosyakov
    • 1
  • S. A. Pokryshkin
    • 1
  • K. G. Bogolitsyn
    • 1
  1. 1.Northern (Arctic) Federal University named after M.V. LomonosovArkhangelskRussia

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