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Journal of Analytical Chemistry

, Volume 69, Issue 14, pp 1320–1322 | Cite as

Investigation of electrospray stability with a dynamic liquid flow splitter

  • A. N. Arseniev
  • N. V. KrasnovEmail author
  • M. Z. Muradymov
Articles

Abstract

The article gives the results of research of electrospray stability with the use of a dynamic splitting of a flow in the spray area under normal conditions. An acidified water-acetonitrile solution (1: 1) was used as an eluant. Experimental results for the used configuration of electrospray junction with a coaxial selection of fluid excess as a steam-gas mixture taken out of the dispersion area (meniscus fluid on the butt-end of a capillary) in the compass of a fluid flow along the capillary from 50 up to 200 μL/min showed more stable relation of an atomized solution flow in comparison with a mode without use of a dynamic splitting of an atomized fluid flow.

Keywords

liquid electrospray dynamic splitting of fluid flow eluate 

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References

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    Samokish, V.A., Krasnov, N.V., and Muradymov, M.Z., Rapid Commun. Mass Spectrom., 2013, vol. 27, no. 8, p. 904.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2014

Authors and Affiliations

  • A. N. Arseniev
    • 1
  • N. V. Krasnov
    • 1
    Email author
  • M. Z. Muradymov
    • 1
  1. 1.Institute for Analytical InstrumentationRussian Academy of SciencesSt. PetersburgRussia

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