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Journal of Analytical Chemistry

, Volume 64, Issue 8, pp 786–790 | Cite as

Preconcentration of Cd(II), Pb(II), Co(II), Ni(II), and Cu(II) by solid-phase extraction method using 1,10-phenanthroline

  • B. Puzio
  • B. Mikula
  • B. Feist
Articles

Abstract

Solid-phase extraction (SPE) method for preconcentration and determination of Cd(II), Pb(II), Co(II), Ni(II), and Cu(II) aqueous samples by inductively coupled plasma optical emission spectrometry is described. The preconcentration of analytes is accomplished by retention of their chelates with 1.10-phenanthroline in aqueous solution on a solid phase containing carboxylic acid (COOH) bonded to silica gel in a column. The limits of detection values (defined as “3s” where “s” is standard deviation of the blank determination) are 3.6 μg/L for Cd(II), 17.5 μg/L for Pb(II), 3.1 μg/L for Co(II), 2.1 μg/L for Ni(II), and 4.4 μg/L for Cu(II) and corresponding limit of quantification (6s) values are 7.2, 35, 6.2, 4.2 and 8.8 μg/L, respectively. As a result, a simple method was elaborated for the group concentration and determination of the above mentioned metals in reference material and in samples of plant material.

Keywords

Couple Plasma Optical Emission Spectrometry Neocuproine Preconcentration Procedure Sodium Diethyldithiocarbamate Diethyl Ammonium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Saraçoǧlu, S. and Elci, L., Anal. Chim. Acta, 2002, vol. 452, p. 77.CrossRefGoogle Scholar
  2. 2.
    Ramesh, A., Mohan, K.R., Seshaiah, K., Talanta, 2002, vol. 57, p. 243.CrossRefGoogle Scholar
  3. 3.
    Comber, S., Analyst, 1993, vol. 118, p. 505.CrossRefGoogle Scholar
  4. 4.
    Mikula, B., Puzio, B., Annals of the Polish Chemicals Society, 2001, p. 239.Google Scholar
  5. 5.
    Ali, A., Yin, X., Shen, H., Ye, Y., Gu, X., Anal. Chim. Acta, 1999, vol. 392, p. 283.CrossRefGoogle Scholar
  6. 6.
    Castro, M.T.P.O., Baccan, N., Talanta, 2005, vol. 65, p. 1264.CrossRefGoogle Scholar
  7. 7.
    Yoshimura, K., Matsuoka, S., Inokura, Y., Hase, U., Anal. Chim. Acta, 1992, vol. 268, p. 225.CrossRefGoogle Scholar
  8. 8.
    Mikula, B., Puzio, B., Talanta, 2007, vol. 71, p. 136.CrossRefGoogle Scholar
  9. 9.
    Sturgeor, R.E., Berman, S.S., Willie, S.N., Talanta, 1982, vol. 29, p. 167.CrossRefGoogle Scholar
  10. 10.
    Liu, Z.S., Huang, S.D., Anal. Chim. Acta, 1993, vol. 281, p. 185.CrossRefGoogle Scholar
  11. 11.
    Abollino, O., Mentasti, E., Pata, V., Sarzanini, C., Anal. Chem., 1990, vol. 62, p. 21.CrossRefGoogle Scholar
  12. 12.
    Abou-El-Sherbini, K.S., Kenawy, I.M.M., Hamed, M.A., Issa, R.M., Elmorsi, R., Talanta, 2002, vol. 58, p. 289.CrossRefGoogle Scholar
  13. 13.
    Narin, I., Soylak, M., Talanta, 2003, vol. 60, p. 215.CrossRefGoogle Scholar
  14. 14.
    Molina, M.F., Bosque-Sendra, J.M., Nechar, M., El Bergmi, R., Anal. Chim. Acta, 1999, vol. 389, p. 281.CrossRefGoogle Scholar
  15. 15.
    Liu, Z.S., Huang, S.D., Anal. Chim. Acta, 1992, vol. 267, p. 31.CrossRefGoogle Scholar
  16. 16.
    Yamini, Y., Tamaddon, A., Talanta, 1999, vol. 49, p. 119.CrossRefGoogle Scholar
  17. 17.
    Hassan, K., Mir, F.M., Yadollah, Y., Mojtaba, S., Anal. Chim. Acta, 2004, vol. 509, p. 89.CrossRefGoogle Scholar
  18. 18.
    Irth, H., de Jong, G.J., Brinkman, U.A.Th., Frei, R.W., Anal. Chem., 1987, vol. 59, p. 98.CrossRefGoogle Scholar
  19. 19.
    Pourreza, N., Hoveizavi, R., Anal. Chim. Acta., 2005, vol. 549, p. 124.CrossRefGoogle Scholar
  20. 20.
    Kaur V., Aulakh J.S., Malik A.K., Anal. Chim. Acta, 2007, vol. 603, p. 44.CrossRefGoogle Scholar
  21. 21.
    Praveena R.S., Naidub G.R.K., Prasada Raoa, T. Anal. Chim. Acta, 2007, vol. 600, p. 205.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • B. Puzio
    • 1
  • B. Mikula
    • 1
  • B. Feist
    • 1
  1. 1.Institute of ChemistrySilesian UniversityKatowicePoland

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