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Colloid Journal

, Volume 81, Issue 6, pp 650–661 | Cite as

Thermodynamic Properties of Water−Ethanol Films Formed between Hydrophobic Surfaces. Part I.

  • Jan Christer ErikssonEmail author
  • Xia Zhenbo
  • Roe-Hoan Yoon
Article
  • 1 Downloads

Abstract

Based on thermodynamic reasoning we claim that long-ranged, solvophobic surface forces may arise in thin films of associated liquids due to formation of linear aggregates composed of spheroidal, nano-sized molecular clusters. Supposedly, these aggregates can span a narrow gap between two hydrofobic solid surfaces submerged in the film-forming liquid phase, thus giving rise to attraction. Such aggregates are apparantly generated in thin water and water–ethanol films, especially below room temperature and for high mole fractions of water or ethanol, respectively. The surface force recorded for a pure water with film thickness larger than about 20 nm are found to be proportional to the number of bridging cluster aggregates per unit area that cross the mid-plane of a thin film. Moreover, the long-range-ness (decay length) was seen to depend inversely on the work of formation of the elongated middle part of a bridging cluster aggregate. Furthermore, addition of small amounts of ethanol rapidly reduce the surface force generated for pure water films with thickness of a few hundred nm.

Notes

ACKNOWLEDGEMENTS

The authors wishes to gratefully thank Prof. Ulf Henriksson , KTH, Stockholm, Sweden, for perusing an early version of this paper, and Prof. Anatoly I. Rusanov, Saint Petersburg, for valuable advice concerning some theoretical matters.

CONFLICT OF INTEREST

The authors declare that they have no conflicts of interest.

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Copyright information

© Pleiades Publishing, Ltd. 2019

Authors and Affiliations

  • Jan Christer Eriksson
    • 1
    Email author
  • Xia Zhenbo
    • 2
  • Roe-Hoan Yoon
    • 2
  1. 1.Division of Surface and Corrosion Science, KTH Royal Institute of TechnologyStockholmSweden
  2. 2.Department of Material Science and Engineering and Department of Mining and Minerals Engineering, Virginia TechBlacksburgUSA

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