Advertisement

Colloid Journal

, Volume 80, Issue 6, pp 783–791 | Cite as

Stabilization of Oil-in-Water Pickering Emulsions with Surfactant-Modified SiO2 Nanoparticles

  • M. Yu. KorolevaEmail author
  • D. A. Bydanov
  • E. V. Yurtov
Article
First Online:

Abstract

Stabilization of Pickering emulsions with silica nanoparticles modified with nonionic surfactants, namely, Tween 20, Tween 40, and Tween 80; cationic cetyltrimethylammonium bromide; and anionic sodium oleate and oleic acid has been studied. The modification of positively charged Ludox CL nanoparticles and negatively charged Ludox HS-30 nanoparticles with sodium oleate and oleic acid has not led to the formation of stable emulsions at dispersion medium pH values of 2–8. The modification of Ludox CL nanoparticles with Tween 20, Tween 40, Tween 80, and cetyltrimethylammonium bromide also has not increased the stability of the emulsions. The stability of the emulsions stabilized with Ludox HS-30 nanoparticles has increased noticeably in the presence of Tween 20, Tween 40, Tween 80, or cetyltrimethylammonium bromide. These surfactants promote the formation of gel-like networks from aggregated Ludox HS-30 nanoparticles in the dispersion media of the emulsions, thereby leading to the formation of emulsions stable with respect to both coalescence and creaming.

This is a preview of subscription content, log in to check access.

Notes

ACKNOWLEDGMENTS

This work was supported by the Ministry of High Education and Science of the Russian Federation within the framework of a state assignment (contract no. 10.4650.2017/6.7) and the Russian Foundation for Basic Research (project no. 16-03-00658).

REFERENCES

  1. 1.
    Binks, B.P., Curr. Opin. Colloid Interface Sci., 2002, vol. 7, p. 21.CrossRefGoogle Scholar
  2. 2.
    Aveyard, R., Binks, B.P., and Clint, J.H., Adv. Colloid Interface Sci., 2003, vols. 100–102, p. 503.Google Scholar
  3. 3.
    Grate, J.W., Warner, M.G., Pittman, J.W., Dehoff, K.J., Wietsma, T.W., Zhang, C., and Oostrom, M., Water Resour. Res., 2013, vol. 49, p. 4724.CrossRefGoogle Scholar
  4. 4.
    Balard, H., Papirer, E., Khalfi, A., and Barthel, H., Compos. Interfaces, 1998, vol. 6, p. 19.Google Scholar
  5. 5.
    Sun, Q., Li, Z., Li, S., Jiang, L., Wang, J., and Wang, P., Energy Fuels, 2014, vol. 28, p. 2384.CrossRefGoogle Scholar
  6. 6.
    Maas, M., Silvério, C.C., Laube, J., and Rezwan, K., J. Colloid Interface Sci., 2017, vol. 501, p. 256.CrossRefGoogle Scholar
  7. 7.
    Saleh, N., Sarbu, T., Sirk, K., Lowry, G.V., Matyjaszewski, K., and Tilton, R.D., Langmuir, 2005, vol. 21, p. 9873.CrossRefGoogle Scholar
  8. 8.
    Binks, B.P., Liu, W., and Rodrigues, J.A., Langmuir, 2008, vol. 24, p. 4443.CrossRefGoogle Scholar
  9. 9.
    Binks, B.P., Rodrigues, J.A., and Frith, W.J., Langmuir, 2007, vol. 23, p. 3626.CrossRefGoogle Scholar
  10. 10.
    Zhu, Y., Jiang, J., Liu, K., Cui, Z., and Binks, B.P., Langmuir, 2015, vol. 31, p. 3301.CrossRefGoogle Scholar
  11. 11.
    Binks, B.P. and Rodrigues, J.A., Langmuir, 2007, vol. 23, p. 7436.CrossRefGoogle Scholar
  12. 12.
    Whitby, C.P., Fornasiero, D., and Ralston, J., J. Colloid Interface Sci., 2009, vol. 329, p. 173.CrossRefGoogle Scholar
  13. 13.
    Li, J. and Stöver, H.D.H., Langmuir, 2008, vol. 24, p. 13 237.CrossRefGoogle Scholar
  14. 14.
    Santini, E., Guzmán, E., Ferrari, M., and Liggieri, L., Colloids Surf. A, 2014, vol. 460, p. 333.CrossRefGoogle Scholar
  15. 15.
    Sadeghpour, A., Pirolt, F., and Glatter, O., Langmuir, 2013, vol. 29, p. 6004.CrossRefGoogle Scholar
  16. 16.
    Zhu, Y., Fu, T., Liu, K., Lin, Q., Pei, X., Jiang, J., Cui, Z., and Binks, B.P., Langmuir, 2017, vol. 33, p. 5724.CrossRefGoogle Scholar
  17. 17.
    Koroleva, M., Gorbachevski, O., and Yurtov, E., Mater. Chem. Phys., 2017, vol. 202, p. 1.CrossRefGoogle Scholar
  18. 18.
    Sun, Q., Li, Z., Li, S., Jiang, L., Wang, J., and Wang, P., Energy Fuels, 2014, vol. 28, p. 2384.CrossRefGoogle Scholar
  19. 19.
    Despert, G. and Oberdisse, J., Langmuir, 2003, vol. 19, p. 7604.CrossRefGoogle Scholar
  20. 20.
    Eskandar, N.G., Simovic, S., and Prestidge, C.A., J. Colloid Interface Sci., 2011, vol. 358, p. 217.CrossRefGoogle Scholar
  21. 21.
    Midmore, B.R., Colloids Surf. A, 1998, vol. 132, p. 257.CrossRefGoogle Scholar
  22. 22.
    Alison, L., Ruhs, P.A., Tervoort, E., Teleki, A., Zanini, M., Isa, L., and Studart, A.R., Langmuir, 2016, vol. 32, p. 13 446.CrossRefGoogle Scholar
  23. 23.
    Koroleva, M.Yu., Bydanov, D.A., Palamarchuk, K.V., and Yurtov, E.V., Colloid J., 2018, vol. 80, p. 282.CrossRefGoogle Scholar
  24. 24.
    Gmür, T.A., Goel, A., and Brown, M.A., J. Phys. Chem. C, 2016, vol. 120, p. 16 617.CrossRefGoogle Scholar
  25. 25.
    Van der Meeren, P., Saveyn, H., Kassa, S.B., Doyen, W., and Leysen, R., Phys. Chem. Chem. Phys., 2004, vol. 6, p. 1408.CrossRefGoogle Scholar
  26. 26.
    Ho, O.B., J. Colloid Interface Sci., 1998, vol. 198, p. 249.CrossRefGoogle Scholar
  27. 27.
    Miraglia, D.B., Rodriguez, J.L., Minardi, R.M., and Schulz, P.C., J. Surfact. Deterg., 2011, vol. 14, p. 401.CrossRefGoogle Scholar
  28. 28.
    Kruglyakov, P.M., Hydrophile-Lipophile Balance of Surfactants and Solid Particles, Amsterdam: Elsevier, 2000.Google Scholar
  29. 29.
    Yurtov, E.V. and Koroleva, M.Yu., ACS Symp. Ser., 1996, vol. 642, p. 89.CrossRefGoogle Scholar
  30. 30.
    Koroleva, M., Tokarev, A., and Yurtov, E., Colloids Surf. A, 2015, vol. 481, p. 237.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Inc. 2018

Authors and Affiliations

  • M. Yu. Koroleva
    • 1
    Email author
  • D. A. Bydanov
    • 1
  • E. V. Yurtov
    • 1
  1. 1.Mendeleev University of Chemical Technology of RussiaMoscowRussia

Personalised recommendations

Cite article

Buy options