Colloid Journal

, Volume 80, Issue 6, pp 751–760 | Cite as

Features of the Interaction between Dodecyltrimethylammonium Bromide Micelles and Sodium 4-Styrene Sulfonate

  • Yu. V. ShulevichEmail author
  • Yu. A. Zakharova
  • M. V. Motyakin
  • I. S. Ionova
  • E. G. Dukhanina
  • A. V. Navrotskii
  • I. A. Novakov


Spin probe EPR spectroscopy and UV spectroscopy have been employed to study the interaction between a hydrophobic anionic monomer, sodium styrene sulfonate, and micelles of a cationic surfactant, dodecyltrimethylammonium bromide. It has been shown that the interaction with the monomer decreases the critical micelle concentration of the surfactant in aqueous solutions. It has been found that the monomer is incorporated into micelles; therefore, the presence of the surfactant may hinder polymerization of the monomer.



This work was supported by Grant of the President of the Russian Federation (no. MK-2017.2017.3) and a state assignment of the Federal Agency for Scientific Organizations of the Russian Federation 0082-2018-0006 (no. AAAA-A18-118020890097-1).


  1. 1.
    Papisov, I.M., Polym. Sci., Ser. B, 1997, vol. 39, p. 122.Google Scholar
  2. 2.
    Polowinski, S., Prog. Polym. Sci., 2002, vol. 27, p. 537.CrossRefGoogle Scholar
  3. 3.
    Motyakin, M.V., Shulevich, Yu.V., Zakharova, Yu.A., Vasserman, A.M., Navrotskii, A.V., and Novakov, I.A., Colloid J., 2009, vol. 71, p. 672.CrossRefGoogle Scholar
  4. 4.
    Shulevich, Yu.V., Motyakin, M.V., Zakharova, Yu.A., Dukhanina, E.G., Vasserman, A.M., Navrotskii, A.V., and Novakov, I.A., Colloid J., 2015, vol. 77, p. 108.CrossRefGoogle Scholar
  5. 5.
    Novakov, I.A., Shulevich, Yu.V., Zakharova, Yu.A., Tkhi Doan Chang, Dukhanina, E.G., and Navrotskii, A.V., Izv. Akad. Nauk, Ser. Khim., 2015, p. 597.Google Scholar
  6. 6.
    Gao, Z., Kwak, J.C.T., and Wasylishen, R.E., J. Colloid Interface Sci., 1988, vol. 126, p. 371.CrossRefGoogle Scholar
  7. 7.
    Vasserman, A.M., Usp. Khim., 1994, vol. 63, p. 391.Google Scholar
  8. 8.
    Livshits, V.A. and Dzikovskii, B.G., Zh. Fiz. Khim., 1994, vol. 68, p. 1650.Google Scholar
  9. 9.
    Saracino, G.A.A., Tedeschi, A., D’Errico, G., Improta, R., Franco, L., Ruzzi, M., Corvaia, C., and Barone, V., J. Phys. Chem. A, 2002, vol. 106, p. 10700.CrossRefGoogle Scholar
  10. 10.
    Budil, D.E., Lee, S., Saxena, S., and Freed, J.H., J. Magn. Reson. A, 1996, vol. 120, p. 155.CrossRefGoogle Scholar
  11. 11.
    Spin Labeling. Theory and Applications, Berliner, L., Ed., New York: Academic, 1976; Moscow: Mir, 1979.Google Scholar
  12. 12.
    Buchachenko, A.L. and Vasserman, A.M., Stabil’nye radikaly (Stable Radicals), Moscow: Khimiya, 1973.Google Scholar
  13. 13.
    Hayakawa, K., Fukutome, T., and Satake, I., Langmuir, 1990, vol. 6, p. 1495.CrossRefGoogle Scholar
  14. 14.
    Hayakawa, K., Shinohara, S., Sasawaki, S., Satake, I., and Kwak, J., Bull. Chem. Soc. Jpn., 1995, vol. 68, p. 2183.CrossRefGoogle Scholar
  15. 15.
    Shulevich, Yu.V., Kovaleva, O.Yu., Navrotskii, A.V., Zakharova, Yu.A., Zezin, A.B., and Novakov, I.A., Polym. Sci., Ser. A, 2007, vol. 49, p. 1284.CrossRefGoogle Scholar
  16. 16.
    Zakharova, J.A., Novoskoltseva, O.A., Pyshkina, O.A., Karpushkin, E.A., and Sergeyev, V.G., Colloid Polym. Sci., 2018, vol. 296, p. 835.CrossRefGoogle Scholar
  17. 17.
    Williamson, C.E. and Corwin, A.H., J. Colloid Interface Sci., 1972, vol. 38, p. 567.CrossRefGoogle Scholar
  18. 18.
    Hooshyar, H. and Sadeghi, R., J. Chem. Eng. Data, 2015, vol. 60, p. 983.CrossRefGoogle Scholar
  19. 19.
    Bilski, P., Dabestani, R., and Chignell, C.F., J. Phys. Chem., 1991, vol. 95, p. 5784.CrossRefGoogle Scholar
  20. 20.
    Bhat, M. and Gaikar, V.G., Langmuir, 1999, vol. 15, p. 4740.CrossRefGoogle Scholar
  21. 21.
    Popov, A., Zakharova, J., Wasserman, A., Motyakin, M., and Kasaikin, V., J. Phys. Chem. B, 2012, vol. 116, p. 12332.CrossRefGoogle Scholar
  22. 22.
    Itaya, T., Ochiai, H., Ueda, K., and Imamura, A., Macromolecules, 1993, vol. 26, p. 6021.CrossRefGoogle Scholar
  23. 23.
    Kubota, M. and Ono, A., Tetrahedron Lett., 2004, vol. 45, p. 1187.CrossRefGoogle Scholar
  24. 24.
    Shulevich, Yu.V., Il’in, S.O., Dukhanina, E.G., Ozerin, A.S., Tutaev, D.S., Navrotskii, A.V., Kulichikhin, V.G., and Novakov, I.A., Izv. Akad. Nauk, Ser. Khim., 2016, p. 1161.Google Scholar

Copyright information

© Pleiades Publishing, Inc. 2018

Authors and Affiliations

  • Yu. V. Shulevich
    • 1
    Email author
  • Yu. A. Zakharova
    • 2
  • M. V. Motyakin
    • 3
  • I. S. Ionova
    • 3
  • E. G. Dukhanina
    • 1
  • A. V. Navrotskii
    • 1
  • I. A. Novakov
    • 1
  1. 1.Volgograd State Technical UniversityVolgogradRussia
  2. 2.Department of Chemistry, Moscow State UniversityMoscowRussia
  3. 3.Semenov Institute of Chemical Physics, Russian Academy of SciencesMoscowRussia

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